Animated Solution for Chemistry - Atomic Structure: A proton and a Li3+ nucleus are accelerated by the same potential. If λLi and λp denote the de-Broglie wavelengths of Li3+ and proton respectively, then the value of λpλLi is x×10−1. The value of x is ......... .
(Rounded off to the nearest integer)
(Mass of Li3+=8.3 mass of proton)
Enter Numerical Value:
Visualized Solution
Visualizing the Setup
Proton (p+) and Lithium nucleus (Li3+)
Accelerated by same potential V
Kinetic Energy Gained
K=qV
de-Broglie Wavelength
λ=ph
λ=2mKh
Master Equation
λ=2mqVh
Ratio of Wavelengths
λpλLi=2mpqpVh2mLiqLiVh
λpλLi=mLiqLimpqp
Substituting Values
qp=e
qLi=3e
mLi=8.3mp
λpλLi=8.3mp⋅3emp⋅e
Simplifying the Expression
λpλLi=8.3×31
λpλLi=24.91
Approximation
24.9≈25
λpλLi≈251
λpλLi=51=0.2
Final Answer
0.2=2×10−1
x×10−1=2×10−1
x=2
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The Sigma Insight: Wave Particle Duality
Solution Diagram
The Setup
Particles in a Potential Field
Imagine a fascinating race at the subatomic level. On one track, we have a solitary proton (p+). On the parallel track, a much heavier contender: a Lithium nucleus (Li3+). Both particles start from rest and are subjected to the exact same accelerating potential difference, V.
When a charged particle accelerates through a potential difference, the electrical work done on it is entirely converted into its kinetic energy. This fundamental principle of electrostatics gives us our first crucial equation:
K=qV
Here, K is the kinetic energy, q is the charge of the particle, and V is the accelerating potential.
The Master Equation
Bridging Particles and Waves
Now, we enter the quantum realm. According to Louis de Broglie's revolutionary hypothesis, every moving particle exhibits wave-like properties. The wavelength λ of this matter wave is inversely proportional to the particle's momentum p:
λ=ph
Since momentum can be expressed in terms of kinetic energy as p=2mK, we can substitute our earlier expression for kinetic energy (K=qV) into the de Broglie equation. This yields a powerful master equation that directly links the quantum wavelength to the macroscopic accelerating potential:
λ=2mqVh
The Ratio
Elegance in Cancellation
Our goal is to find the ratio of the wavelength of the Lithium nucleus to that of the proton, λpλLi. Let's set up the ratio using our master equation:
λpλLi=2mpqpVh2mLiqLiVh
Notice the mathematical elegance here! Planck's constant h, the number 2, and the accelerating potential V are identical for both particles. They beautifully cancel out, leaving us with a much simpler relationship depending only on the mass and charge of the particles:
λpλLi=mLiqLimpqp
The Final Calculation
The Art of Approximation
Now, we plug in the specific values given in the problem. The charge of a proton is e, and the charge of the Li3+ nucleus is 3e. The problem also explicitly states that the mass of the Lithium nucleus is 8.3 times the mass of a proton (mLi=8.3mp). Substituting these into our ratio:
λpλLi=8.3mp⋅3emp⋅e
The mass of the proton (mp) and the elementary charge (e) cancel out from the numerator and denominator. We are left with a pure numerical fraction:
λpλLi=8.3×31=24.91
Here is where a bit of exam intuition comes into play. The number 24.9 is incredibly close to 25, which is a perfect square. In competitive physics and chemistry, this is a deliberate signal to approximate:
λpλLi≈251=51=0.2
The question asks for the answer in the format x×10−1. Since 0.2 is exactly 2×10−1, we can confidently conclude that x=2.