Sigma Percentile
JEE Main 2021
LEVELJEE Main

Animated Solution for Chemistry - Atomic Structure: A proton and a nucleus are accelerated by the same potential. If and denote the de-Broglie wavelengths of and proton respectively, then the value of is . The value of is ......... . (Rounded off to the nearest integer) (Mass of mass of proton)

Enter Numerical Value:

Visualized Solution

  • Proton () and Lithium nucleus ()
  • Accelerated by same potential

The Sigma Insight: Wave Particle Duality

Solution Diagram

The Setup

Particles in a Potential Field
Imagine a fascinating race at the subatomic level. On one track, we have a solitary proton (). On the parallel track, a much heavier contender: a Lithium nucleus (). Both particles start from rest and are subjected to the exact same accelerating potential difference, .
When a charged particle accelerates through a potential difference, the electrical work done on it is entirely converted into its kinetic energy. This fundamental principle of electrostatics gives us our first crucial equation:
Here, is the kinetic energy, is the charge of the particle, and is the accelerating potential.

The Master Equation

Bridging Particles and Waves
Now, we enter the quantum realm. According to Louis de Broglie's revolutionary hypothesis, every moving particle exhibits wave-like properties. The wavelength of this matter wave is inversely proportional to the particle's momentum :
Since momentum can be expressed in terms of kinetic energy as , we can substitute our earlier expression for kinetic energy () into the de Broglie equation. This yields a powerful master equation that directly links the quantum wavelength to the macroscopic accelerating potential:

The Ratio

Elegance in Cancellation
Our goal is to find the ratio of the wavelength of the Lithium nucleus to that of the proton, . Let's set up the ratio using our master equation:
Notice the mathematical elegance here! Planck's constant , the number , and the accelerating potential are identical for both particles. They beautifully cancel out, leaving us with a much simpler relationship depending only on the mass and charge of the particles:

The Final Calculation

The Art of Approximation
Now, we plug in the specific values given in the problem. The charge of a proton is , and the charge of the nucleus is . The problem also explicitly states that the mass of the Lithium nucleus is times the mass of a proton (). Substituting these into our ratio:
The mass of the proton () and the elementary charge () cancel out from the numerator and denominator. We are left with a pure numerical fraction:
Here is where a bit of exam intuition comes into play. The number is incredibly close to , which is a perfect square. In competitive physics and chemistry, this is a deliberate signal to approximate:
The question asks for the answer in the format . Since is exactly , we can confidently conclude that .

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