Animated Solution for Chemistry - Atomic Structure: A stream of electrons from a heated filament was passed between two charged plates kept at a potential difference V esu. If e and m are charge and mass of an electron, respectively, then the value of h/λ (where, λ is wavelength associated with electron wave) is given by
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Visualized Solution
\text{Electron Acceleration}
An electron of mass m and charge e is accelerated through a potential difference V.
\text{Kinetic Energy Gained}
K=eV
\text{Kinetic Energy and Momentum}
K=2mp2
\text{Calculating Momentum}
2mp2=eV
p=2meV
\text{de-Broglie Wavelength}
λ=ph
\text{Substituting Momentum}
λ=2meVh
\text{Final Expression}
λh=2meV
\text{The Way Forward}
What if the particle was a proton or an alpha particle?
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The Sigma Insight: Wave Particle Duality
Solution Diagram
The Setup
Accelerating the Electron
Imagine an electron, a tiny negatively charged particle, sitting quietly at a heated filament (the cathode). Suddenly, we introduce a potential difference, V, between the cathode and a nearby anode. The electron feels an irresistible pull towards the positive anode and begins to accelerate, tearing across the gap.
As it moves through this electric field, the electrical work done on the electron is entirely converted into its kinetic energy. This is a beautiful demonstration of the conservation of energy. The kinetic energy K gained by the electron is simply the product of its charge e and the potential difference V:
K=eV
The Classical Bridge
Energy and Momentum
Now, let's look at this from the perspective of classical mechanics. We know that the kinetic energy of a moving particle can also be expressed in terms of its momentum, p. Instead of the familiar 21mv2, we can write it as:
K=2mp2
This is a super useful relation because it directly connects energy to momentum, which is exactly what we need for the next step. By equating our two expressions for kinetic energy, we can find the momentum the electron has gained:
2mp2=eV
Solving for momentum p, we get:
p=2meV
The Quantum Leap
Matter Waves
Here comes the quantum twist! In 1924, Louis de Broglie proposed a radical idea: if light waves can act like particles (photons), then particles like electrons should be able to act like waves. He suggested that every moving particle has an associated "matter wave."
The wavelength λ of this matter wave is inversely proportional to the particle's momentum p, connected by Planck's constant h:
λ=ph
Bringing It All Together
Now, we just need to synthesize our classical momentum with our quantum wavelength. Let's substitute the momentum p we found earlier into the de Broglie equation:
λ=2meVh
The question specifically asks for the value of the expression λh. To find this, we simply rearrange our final equation. By multiplying both sides by 2meV and dividing by λ, we arrive at our final answer:
λh=2meV
This elegant result shows how the quantum properties of an electron are directly tied to the macroscopic voltage we apply to it. It perfectly matches option (c)!