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JEE Main 2019
LEVELJEE Advanced

Animated Solution for Chemistry - Atomic Structure: What is the work function of the metal, if the light of wavelength generates photoelectron of velocity from it? (Mass of electron Velocity of light Planck's constant Charge of electron )

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Visualized Solution

\text{The Photoelectric Setup}

\text{Einstein's Photoelectric Equation}

\text{Energy of Incident Photon}

\text{Kinetic Energy of Electron}

\text{Calculating Work Function}

\text{Conversion to Electron-Volts}

\text{The Way Forward}

The Sigma Insight: Wave Particle Duality

Solution Diagram

The Setup

Light Meets Metal
Imagine you are observing a microscopic game of pinball. A beam of light, acting as a stream of energetic particles called photons, strikes a metal surface. If a photon hits an electron with enough energy, it knocks the electron right out of the metal! This fascinating phenomenon is known as the photoelectric effect.
In our specific problem, we are given a light beam with a wavelength . When this light hits the metal, it ejects an electron that zooms away with a velocity . Our mission is to find the work function () of the metal, which is the minimum energy required just to pull an electron free from the surface.

The Master Equation

Einstein's Genius
To solve this, we turn to Albert Einstein's elegant photoelectric equation. It states that the total energy of the incident photon () is conserved and split into two parts: the energy used to overcome the work function (), and the remaining energy which becomes the kinetic energy () of the ejected electron.
Rearranging this to solve for the work function, we get:
This means we need to calculate the photon's energy and the electron's kinetic energy separately, and then simply subtract them.

Crunching the Numbers

Photon Energy
First, let's calculate the energy of the incoming photon using the formula . We must be careful to convert the wavelength from Angstroms to meters by multiplying by .
By carefully multiplying the constants and managing the powers of ten, we find:

The Electron's Escape

Kinetic Energy
Next, we determine the kinetic energy of the ejected electron using the classic mechanics formula . We plug in the mass of the electron and its given velocity.
Squaring the velocity gives . Multiplying everything together yields:
To make subtraction easier later, we adjust the decimal to match the power of ten of the photon's energy:

The Final Reveal

Calculating the Work Function
Now, we substitute our calculated values back into our rearranged photoelectric equation.
We have the work function in Joules, but our multiple-choice options are in electron-volts (eV). To convert Joules to eV, we divide by the charge of an electron ().
The powers of ten cancel out beautifully, leaving us with:
Rounding to one decimal place, we get , which perfectly matches option (b). The physics holds true, and the math confirms it!

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