Sigma Percentile
JEE Main 2019
LEVELJEE Main

Animated Solution for Chemistry - Atomic Structure: If is the momentum of the fastest electron ejected from a metal surface after the irradiation of light having wavelength , then for momentum of the photoelectron, the wavelength of the light should be (Assume kinetic energy of ejected photoelectron to be very high in comparison to work function)

Select Answer:

Visualized Solution

The Sigma Insight: Wave Particle Duality

Solution Diagram

The Photoelectric Setup

Imagine a photon of light acting like a tiny billiard ball, striking a metal surface and knocking an electron out. This is the essence of the photoelectric effect.
The energy of the incoming photon is split into two parts: overcoming the metal's binding energy (the work function, ), and giving the ejected electron its kinetic energy ().
Mathematically, this is Einstein's famous equation:

The Crucial Approximation

The problem gives us a massive shortcut. It states that the kinetic energy of the ejected photoelectron is very high in comparison to the work function.
What does this mean for our equation? It means is negligibly small compared to .
We can safely approximate the equation to:
This simplifies our life immensely!

Bridging Energy and Momentum

Now, we need to connect the properties of the light to the properties of the electron.
For the incident light, the energy of a photon is given by , where is Planck's constant, is the speed of light, and is the wavelength.
For the ejected electron, its kinetic energy can be expressed in terms of its momentum . Using the relation and , we get .

The Master Equation

Let's bring it all together. By equating the photon's energy to the electron's kinetic energy, we get:
Rearranging this to solve for wavelength , we find:
Notice that , , , and are all constants. This reveals a beautiful inverse square relationship:

Final Calculation

We are asked to find the new wavelength when the momentum becomes .
Using our proportionality, we can set up a ratio between the two states:
Substitute the given values: and .
Since , the ratio becomes . Squaring this gives us:
Therefore, the new wavelength is . This perfectly matches option (a).

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