Sigma Percentile
JEE Advanced 2021
LEVELJEE Main

Animated Solution for Chemistry - Atomic Structure: Consider a helium (He) atom that absorbs a photon of wavelength . The change in the velocity (in ) of He atom after the photon absorption is ______. (Assume: Momentum is conserved when photon is absorbed. [Use: Planck constant , Avogadro number , Molar mass of He ]

Enter Numerical Value:

Visualized Solution

Visualizing the Collision

  • Initial state: Photon approaches stationary He atom.
  • Final state: He atom absorbs photon and recoils.

Momentum of a Photon

Calculating Photon Momentum

Evaluating Photon Momentum

Mass of a Single He Atom

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Evaluating Mass

Conservation of Momentum

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Substituting Values

Solving for Velocity

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Final Answer in cm/s

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The Way Forward

  • What if the atom emitted a photon instead?
  • Recoil velocity would be identical in magnitude but opposite in direction.

The Sigma Insight: Wave Particle Duality

Solution Diagram
Have you ever wondered what happens when the quantum world collides with classical mechanics? Imagine a tiny, solitary Helium atom floating in the vast emptiness of space, perfectly at rest. Suddenly, a photon—a packet of pure light energy—comes hurtling towards it at the speed of light.
In a fraction of a nanosecond, the Helium atom absorbs the photon completely. But wait! The photon was moving, which means it carried momentum. According to the fundamental laws of the universe, momentum cannot simply vanish. It must be conserved. So, what happens to that momentum? It gets transferred entirely to the Helium atom, causing it to recoil and move.
This beautiful interplay between light and matter is exactly what we are going to unravel in this problem. We will bridge the gap between the wave nature of light and the kinetic motion of an atom. Let's break it down step by step.

Analyzing the Setup

The Photon's Kick
Our journey begins with the incoming photon. Even though a photon has absolutely zero rest mass, it is not devoid of momentum. This is one of the most mind-bending revelations of quantum mechanics, brought to light by Louis de Broglie.
The de Broglie relation tells us that any wave has an associated momentum, and any particle has an associated wavelength. For our photon, this relationship is elegantly captured by the equation:
Here, is Planck's constant, the fundamental pixel size of the quantum universe, and is the wavelength of the light. The problem provides us with a wavelength of . Before we plug this into our equation, we must ensure our units are perfectly aligned. Physics is unforgiving when it comes to mismatched units! We convert nanometers to meters by multiplying by .

Calculating the Photon's Momentum

Let's substitute the given values into our master equation. We have Planck's constant and the wavelength .
To simplify this without getting lost in a sea of zeroes, let's look at the numbers first. divided by is exactly . Now, let's handle the powers of ten. divided by is .
We can rewrite this in a much cleaner scientific notation by shifting the decimal point two places to the right, which decreases the exponent by two:
This incredibly tiny number represents the exact "kick" the photon delivers to the Helium atom upon absorption.

Determining the Mass of a Single Helium Atom

Now that we know the force of the kick, we need to know how heavy the object being kicked is. The problem states that the molar mass of Helium is .
Warning: This is a classic trap! This is the mass of an entire mole of Helium atoms—that's atoms! We only care about one single, solitary atom.
To find the mass of one atom, we must divide the molar mass by Avogadro's number (). Furthermore, to maintain harmony with our standard SI units (since Planck's constant uses kilograms), we must convert the into .
Simplifying the fraction gives us . Subtracting the exponents () gives us .

The Master Equation

Conservation of Momentum
We have all our pieces on the chessboard. We know the momentum of the incoming photon, and we know the mass of the Helium atom. The grand principle of Conservation of Momentum dictates that the total momentum before the collision must equal the total momentum after the collision.
Since the Helium atom was initially at rest, the initial momentum is solely that of the photon. After absorption, the photon is gone, and the Helium atom is moving with a new velocity, .

Final Calculation

Bringing It All Together
Let's substitute our hard-earned values into this conservation equation:
Now, we isolate . We multiply both sides by , divide by , and divide by :
The 's cancel out beautifully. We are left with , which is simply:
The Final Trap: Are we done? Not quite! The examiners have laid one final snare. The question explicitly asks for the velocity in .
To convert meters per second to centimeters per second, we multiply by .
And there we have it! By carefully navigating quantum momentum, atomic mass, and unit conversions, we've successfully calculated the recoil velocity of the atom. The final answer is 30.

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