Decoding the Radioactive Decay Graph
Graphical problems in radioactivity are incredibly elegant because they allow us to visualize exponential decay as simple straight lines. In this problem, we are given a graph of lnR versus time t for three different radioactive substances: A, B, and C. Our goal is to find the ratio of their half-lives.
To do this, we first need to understand the mathematical relationship governing the graph.
The Master Equation
The fundamental law of radioactive decay states that the activity R at any time t is given by:
where R0 is the initial activity and λ is the decay constant.
Because dealing with exponential curves visually is tricky, we linearize the equation by taking the natural logarithm on both sides:
If we compare this to the standard equation of a straight line, y=mx+c, we can immediately see the physical significance of the graph's features:
- The y-axis represents y=lnR.
- The x-axis represents x=t.
- The y-intercept c=lnR0.
- The slope m=−λ.
This means the decay constant λ is simply the negative of the slope of the line!
Calculating the Decay Constants
Let's extract the slopes for each curve directly from the given coordinates.
For Substance A:
The line starts at
(0,6) and ends at
(10,0).
SlopeA=10−00−6=−106
Therefore,
λA=106.
For Substance B:
The line starts at
(0,6) and ends at
(5,0).
SlopeB=5−00−6=−56
Therefore,
λB=56.
For Substance C:
The line starts at
(0,2) and ends at
(5,0).
SlopeC=5−00−2=−52
Therefore,
λC=52.
Finding the Half-Life Ratio
We know that the half-life T1/2 is inversely proportional to the decay constant:
Now, we can write the half-lives for all three substances:
- T1/2(A)=610ln2
- T1/2(B)=65ln2
- T1/2(C)=25ln2
Finally, we take their ratio:
T1/2(A):T1/2(B):T1/2(C)=610:65:25
To clear the denominators, we can multiply the entire ratio by 6:
Dividing by 5, we get our final, beautifully simplified ratio:
This perfectly matches option (d).
As a bonus insight, notice how curves A and B start at the exact same point on the y-axis. This tells us that despite having different half-lives, substances A and B had the exact same initial activity R0 at t=0.