The Phenomenon of Sequential Decay
Imagine a cascading waterfall. The water from the top pool flows into a middle pool, which in turn flows into a bottom pool. This is exactly what happens in sequential radioactive decay.
We start with a parent nucleus A. It is unstable and decays into a daughter nucleus B with a decay constant λA​. But the story doesn't end there. Nucleus B is also radioactive! It decays into a stable nucleus C with its own decay constant λB​.
This creates a dynamic tug-of-war for the population of nucleus B. It is constantly being created by the decay of A, and simultaneously being destroyed by its own decay into C.
The Mathematics of Growth and Decay
To understand how the number of atoms of B (NB​) changes over time, we need to look at its rate equation. The net rate of change of NB​ is the difference between its rate of production and its rate of decay.
dtdNB​​=λA​NA​−λB​NB​
Here, λA​NA​ represents the rate at which B is being formed from A. Since A undergoes standard exponential decay, NA​=N0​e−λA​t. The term λB​NB​ represents the rate at which B is decaying into C.
Analyzing the Graph's Journey
Let's trace the journey of NB​ from the very beginning. At t=0, the problem states there are no B atoms in the sample. So, NB​=0. This means our graph must strictly start from the origin.
In the initial phase, there is an abundance of A atoms and zero B atoms. Therefore, the production rate λA​NA​ is at its maximum, while the decay rate λB​NB​ is zero. The number of B atoms will start to rise rapidly.
As time goes on, NB​ increases, which means its decay rate λB​NB​ also increases. Meanwhile, the pool of A atoms is depleting, so the production rate λA​NA​ is dropping. Eventually, these two rates will perfectly balance each other.
At this exact moment, dtdNB​​=0. The graph reaches its maximum peak.
The Final Phase
After this peak, the parent nucleus A is mostly exhausted. The production of new B atoms slows down to a trickle. However, we now have a large population of B atoms, so they are decaying into C very quickly.
The decay rate now dominates the production rate. The number of B atoms will start to fall. As t→∞, the supply of A becomes negligible, and B simply undergoes standard exponential decay, asymptotically approaching zero.
Therefore, the correct graph must start at the origin, rise to a peak, and then decay exponentially. This perfectly matches the curve shown in option (b).