Decoding the Radioactive Puzzle
Imagine you are a nuclear physicist handed two mysterious radioactive samples, S1 and S2. You place them in your detectors and observe their activities. Sample S1 is ticking away at 5μCi, while sample S2 is twice as active, registering 10μCi. But here is the catch: your mass spectrometer reveals that sample S1 actually contains twice as many radioactive nuclei as sample S2.
How can a sample with more radioactive material be less active? The secret lies in the half-life. Let's unravel this beautiful relationship between activity, population size, and time.
The Law of Radioactive Decay
To solve this mystery, we need to consult the fundamental law of radioactive decay. The activity A of a sample—which is the number of decays per second—is directly proportional to the number of undecayed nuclei N present in the sample. The constant of proportionality is the decay constant λ.
But what exactly is λ? It represents the probability of decay per unit time. We can relate it to a much more intuitive concept: the half-life T1/2, which is the time required for half of the nuclei to decay. The relationship is given by:
Substituting this back into our activity equation, we get a master formula that connects all our variables:
Setting Up the Proportionality
We want to find the half-lives, so let's rearrange our master formula to solve for T1/2:
Since ln2 is just a constant number, we can see a clear proportional relationship: the half-life is directly proportional to the number of nuclei N and inversely proportional to the activity A.
This inverse relationship perfectly explains our initial puzzle! Sample S1 has more nuclei but lower activity because its half-life must be significantly longer. It decays at a much more sluggish pace.
Let's set up a ratio to compare the two samples directly:
T2T1=(N2N1)×(A1A2)
Notice how the activity ratio is inverted (A2/A1) because of the inverse proportionality.
The Final Verdict
Now, it is time for the grand finale. Let's plug in the numbers given to us in the problem. We know that S1 has twice as many nuclei as S2, so:
We also know their activities: A1=5μCi and A2=10μCi. So the inverted activity ratio is:
Substituting these ratios back into our half-life equation:
This tells us that the half-life of sample S1 is exactly four times the half-life of sample S2.
Looking at our multiple-choice options, we need to find a pair of half-lives where the first is four times the second.
- Option (a) offers 20 yr and 5 yr. Since 20/5=4, this is a perfect match!
- Option (b) offers 20 yr and 10 yr, which is a ratio of 2.
- Options (c) and (d) offer equal half-lives, a ratio of 1.
Therefore, the correct answer is undeniably (a). The math elegantly confirms our physical intuition!