Sigma Percentile
JEE Main 2019
LEVELJEE Main

Animated Solution for Chemistry - Atomic Structure: Which of the graphs shown below does not represent the relationship between incident light and the electron ejected from metal surface?

Select Answer:

Visualized Solution

K.E._{max} = h\nu - \Phi

  • Einstein's Photoelectric Equation:

K.E. = E - E_0

  • Graph (a): vs
  • Equation of straight line:
  • Slope
  • x-intercept

K.E. \text{ vs Intensity}

  • Graph (b): vs Intensity
  • is independent of Intensity.
  • Intensity Number of photons per second.

\text{Number of } e^- \text{ vs } \nu

  • Graph (c): Number of vs
  • For , Number of
  • For , Number of depends on intensity.

K.E. = h\nu - h\nu_0

  • Graph (d): vs

\Phi = 0 \text{ ?}

  • If graph passes through origin :
  • But for metals, .

\text{Correct Graph}

  • Correct relationship:
  • x-intercept
  • y-intercept

\text{Conclusion}

  • Option (d) is incorrect.

The Sigma Insight: Wave Particle Duality

Solution Diagram

The Elegance of the Photoelectric Effect

The photoelectric effect is one of the most beautiful phenomena in modern physics, serving as the bedrock for quantum mechanics. When light strikes a metal surface, it can eject electrons, but this process doesn't follow classical wave theory. Instead, it obeys Einstein's elegant photoelectric equation:
Here, is the maximum kinetic energy of the ejected electron, $h u$ is the energy of the incident photon, and (or ) is the work function—the minimum energy required to rip an electron away from the metal's surface.

Decoding the Graphs

To solve this problem, we must act as detectives, interrogating each graph to see if it aligns with physical reality.
Graph A: Kinetic Energy vs. Incident Energy If we rewrite our equation as , it perfectly mirrors the equation of a straight line, . The slope is , and the x-intercept is . Graph A shows exactly this: a straight line starting at a positive energy value. It is a flawless representation.
Graph B: Kinetic Energy vs. Intensity Classical physics predicted that brighter light (higher intensity) would give electrons more energy. Quantum mechanics says no! Intensity merely means more photons are hitting the surface per second, not that individual photons are more energetic. Therefore, the maximum kinetic energy of a single ejected electron is completely independent of intensity. Graph B shows a flat, horizontal line, which is absolutely correct.
Graph C: Number of Electrons vs. Frequency Imagine trying to buy a 10 bills. It doesn't matter how many bills you have; no single bill is enough. Similarly, if the incident light's frequency $ u$ is below the threshold frequency $ u_0$, no electrons are ejected, regardless of intensity. Once $ u \ge u_0$, electrons are emitted, and their number depends on the intensity of the light. This creates a step function, exactly as shown in Graph C.

The Fatal Flaw in Graph D

Finally, we arrive at Graph D, which plots Kinetic Energy against Frequency. According to $K.E. = h u - h u_0$, this should indeed be a straight line. However, look closely at where the line begins.
Graph D shows the line starting precisely at the origin . Mathematically, this implies that when $ u = 0$, . Plugging this into our equation yields:
This suggests the metal has a work function of zero! Physically, this is impossible. Every metal binds its electrons with some finite energy. A correct graph must have a positive x-intercept at $ u_0$ (the threshold frequency) and, if extrapolated, a negative y-intercept at $-h u_0$.
Because Graph D violates this fundamental physical constraint, it is the incorrect representation, making it our final answer.

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