Analyzing the Setup
Let's carefully analyze the given p−V diagram. We are presented with two cyclic processes starting from state E. The path E→F is clearly isochoric as the volume remains constant at V0. From F, the gas expands along two different curves to reach the isobaric line p=p0.
We know from thermodynamics that an adiabatic curve is always steeper than an isothermal curve on a p−V diagram. Therefore, the inner curve F→H must be the adiabatic process, and the outer curve F→G must be the isothermal process.
Finding the Coordinates
To calculate the work done for each path, we first need the exact pressure and volume at every state. From the graph, state E is at (V0,p0) and state F is at (V0,32p0).
Let's find the volume at state G. The path F→G is an isothermal process, which means the product of pressure and volume remains constant. So, pFVF=pGVG. Substituting the known values, we get (32p0)(V0)=(p0)(VG). Solving this, the pressure p0 cancels out, and we get the volume at G as VG=32V0.
Now for state H. The path F→H is an adiabatic process. The governing equation is pVγ=constant. For a monatomic gas, the ratio of specific heats γ is 5/3. So, pFVF5/3=pHVH5/3.
Plugging in the values, we get (32p0)(V0)5/3=(p0)(VH)5/3. The number 32 can be written as 25. Taking the 3/5 power on both sides, we find that the volume at H is exactly VH=(25)3/5V0=8V0.
Calculating the Work Done
Now we are ready to match the lists. Let's start with path P, which is G→E. This is an isobaric compression at pressure p0. The work done is p0 times the change in volume, which is V0−32V0. This gives −31p0V0. The magnitude is 31p0V0, which matches with option 4.
Next is path Q, from G→H. This is also an isobaric compression. The work done is p0 times the final volume 8V0 minus the initial volume 32V0. This equals −24p0V0. Its magnitude is 24p0V0, matching with option 3.
Path R is the adiabatic expansion from F→H. The work done is given by γ−1piVi−pfVf. Substituting the values, we get 5/3−132p0V0−8p0V0. This simplifies to 2/324p0V0, which is 36p0V0. This matches option 2.
Finally, path S is the isothermal expansion from F→G. The work done is nRTln(Vf/Vi), which is also equal to piViln(Vf/Vi). This gives 32p0V0ln(32V0/V0). Since 32 is 25, the 5 comes out, giving 160p0V0ln2. This matches option 1.
Final Conclusion
So, the correct matching is P-4, Q-3, R-2, S-1. This corresponds perfectly to option (a).