Sigma Percentile
JEE Advanced 2010
LEVELJEE Advanced

Animated Solution for Physics - Thermodynamics: One mole of an ideal gas in initial state undergoes a cyclic process , as shown in the figure. Its pressure at is . Choose the correct option(s) from the following.

Select Answer:

* Multiple Correct

Visualized Solution

  • From the graph, process is a vertical line.
  • This means temperature is constant: .
  • Since internal energy of an ideal gas depends only on temperature (), .
  • Therefore, option (a) is correct.

  • Process is an isothermal expansion.
  • Work done:
  • Here, , , , .

  • At state , using the ideal gas equation:
  • Given , , , and .
  • So, .
  • Substituting this into the work equation: .
  • Therefore, option (b) is correct.

  • Process is a straight line on the graph.
  • If the line passed through the origin, we would have , which means pressure is constant (isobaric process).
  • If it were isobaric, .
  • For isothermal process : .
  • Then would be and would be .

  • However, the graph does not explicitly show or state that line passes through the origin.
  • Without this information, we cannot assume .
  • Therefore, the exact pressure and temperature at cannot be determined.
  • Options (c) and (d) are not necessarily correct.

The Sigma Insight: Thermodynamic Processes

Solution Diagram
Welcome to this fascinating journey through thermodynamics! Today, we are going to dissect a beautiful problem involving a cyclic process of an ideal gas. At first glance, graphs can be deceiving, but by carefully analyzing the axes and the physical laws governing the gas, we can unravel the entire story. Let's dive in!

Decoding the V-T Graph

The very first step in tackling any graphical thermodynamics problem is to look at the axes. It is a common pitfall to assume every graph is a (pressure-volume) diagram. Here, the vertical axis represents Volume () and the horizontal axis represents Temperature ().
We are given one mole of an ideal gas undergoing a cyclic process . Let's trace its path. The process starts at state , where the temperature is and the volume is . The pressure at this initial state is given as .

The Isothermal Journey from A to B

Look closely at the line connecting state to state . It is a perfectly vertical line. On a graph, a vertical line means that the temperature is not changing. Therefore, . A process where the temperature remains constant is called an isothermal process.
Now, what does this mean for the internal energy of the gas? The internal energy () of an ideal gas is a function of its absolute temperature alone, given by the relation . Since the temperature at and is exactly the same, their internal energies must also be identical. This confirms that Internal energies at and are the same.
Next, let's calculate the work done during this isothermal expansion. The gas expands from an initial volume to a final volume . The work done in an isothermal process is given by the elegant formula:
Substituting our known values (, , , ), we get:
We can express this in terms of the initial pressure and volume. Using the ideal gas equation at state , we know that , which translates to . Substituting this back into our work equation, we find:
This perfectly matches our second option!

The Ambiguity of Process BC

Now, let's move from state to state . The graph shows a straight line connecting these two points. Here is where many students fall into a trap. It is tempting to assume that this straight line represents an isobaric (constant pressure) process.
For a process to be isobaric on a graph, the volume must be directly proportional to the temperature (), which means the straight line must pass through the origin.
If we assume the line passes through the origin, we could calculate the pressure at . Since is isothermal, , giving us . An isobaric process would mean . Furthermore, using Charles's Law (), we would find .
However, the graph does not explicitly show or state that the line passes through the origin. In physics, we cannot make assumptions based on visual approximations unless explicitly stated. Because of this crucial missing piece of information, we cannot definitively determine the pressure and temperature at state .
Thus, we must conclude that only the first two statements are verifiably correct. This problem is a brilliant reminder to always read graphs carefully and never assume information that isn't explicitly provided!

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