Analyzing the Setup
Imagine you are tracking the journey of a monoatomic gas as it undergoes a series of thermodynamic transformations. The P-V diagram is our map. We start at state A, where the gas is at a pressure of 100 kPa and occupies a volume of 0.80 m3. The gas is then compressed adiabatically to state B, where the pressure spikes to 300 kPa.
Before we can calculate any work, we need to find the missing piece of the puzzle: the volume at state B (VB).
The Adiabatic Compression (A→B)
For an adiabatic process, the relationship between pressure and volume is governed by the equation PAVAγ=PBVBγ. We are given that the gas is monoatomic, so γ=35.
Let's plug in our known values:
100×(0.8)5/3=300×VB5/3
Rearranging to solve for
VB, we get:
VB=0.8×(31)3/5
The problem kindly provides the approximation
(31)0.6≃0.5. Since
3/5 is exactly
0.6, we can easily compute:
VB=0.8×0.5=0.4 m3
Now, let's calculate the work done during this adiabatic compression. The formula is:
WAB=γ−1PAVA−PBVB
Substituting our values:
WAB=5/3−1100(0.8)−300(0.4)=2/380−120=−60 kJ
The negative sign makes perfect physical sense—the gas was compressed, meaning work was done on the gas. The magnitude of this work is 60 kJ, which makes option (C) correct.
The Isothermal Expansion (B→C)
Next, the gas expands isothermally from state B to state C. For an isothermal process, the work done is given by:
WBC=nRTln(VBVC)
Since we don't have the temperature, we can use the ideal gas law (
PV=nRT) to substitute
PBVB for
nRT:
WBC=PBVBln(VBVC)
Looking at the P-V diagram, state C lies on the same vertical dashed line as state A. This means they share the same volume:
VC=VA=0.8 m3. Let's calculate the work:
WBC=300(0.4)ln(0.40.8)=120ln2
Using the given approximation
ln2≃0.7:
WBC=120×0.7=84 kJ
The magnitude of the work done in process B→C is indeed 84 kJ, making option (B) correct.
Closing the Cycle (C→A)
Finally, let's consider the path from C back to A. As we noted earlier, both states lie on the same vertical line, meaning the volume remains constant at 0.8 m3.
This is an
isochoric process. Because there is no change in volume (
ΔV=0), the gas does no work:
WCA=0 kJ
This confirms that option (D) is correct.
To wrap things up, let's check the total work done over the entire path
A→B→C:
Wtotal=WAB+WBC=−60+84=24 kJ
The magnitude of the total work is 24 kJ, not 144 kJ. Therefore, option (A) is incorrect.