Decoding the T−V Graph
Thermodynamic graphs are like maps; they tell us exactly what a gas is experiencing at any given moment. In this problem, we are given a cyclic process plotted on a T−V (Temperature-Volume) graph. To determine which statements are true, we need to translate the geometry of the lines into physical thermodynamic processes.
The Isothermal Phases
Processes II and IV
Let's start with the easiest features to identify: the horizontal lines.
In Process II, the graph moves horizontally to the right. A horizontal line on a T−V graph means the temperature T is constant. This defines an isothermal process. Because the graph moves to the right, the volume V is increasing, making it an isothermal expansion.
For an ideal gas, the internal energy U depends only on temperature. Since ΔT=0, the change in internal energy ΔU=0. The gas is expanding, so it does positive work (W>0). According to the First Law of Thermodynamics:
Since ΔU=0 and W>0, it follows that ΔQ>0. The positive sign indicates that the gas absorbs heat. Therefore, statement (b) is correct.
Similarly, Process IV is a horizontal line moving to the left. This is an isothermal compression (T=constant, V decreases). Here, ΔU=0 and W<0. Consequently, ΔQ<0, meaning the gas releases heat. Thus, statement (c) is also correct.
The Slanted Lines
Are they Isobaric?
Now, let's evaluate the slanted lines, Process I and Process III. Statement (d) claims they are not isobaric. To verify this, we must recall the condition for an isobaric (constant pressure) process on a T−V graph.
From the ideal gas law, PV=nRT, we can rearrange it to solve for temperature:
If the pressure P is constant, the term (nRP) is a constant slope. This equation takes the form y=mx, which represents a straight line that must pass exactly through the origin (0,0).
If we look closely at the given graph and extend the lines for Process I and Process III backwards, they intersect the volume axis at a positive value, not the origin. Because they do not pass through the origin, the pressure is not constant. Therefore, they are not isobaric processes, making statement (d) correct.
Conclusion
Finally, let's quickly check statement (a), which suggests Process I is isochoric. An isochoric process means the volume is constant, which would appear as a perfectly vertical line on a T−V graph. Since Process I is slanted and the volume is clearly changing, statement (a) is incorrect.
By systematically analyzing the geometry of the graph and applying the First Law of Thermodynamics, we confidently conclude that the correct statements are (b), (c), and (d).