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The Sigma Insight: Energy Bands in Solids and Semiconductors
The Tale of Two Materials
Imagine you have two distinct pieces of material sitting on your desk at room temperature: a shiny piece of copper and a dark, crystalline piece of germanium. You decide to plunge both of them into a bath of liquid nitrogen, rapidly cooling them down to a freezing . What happens to their electrical resistance? To answer this, we must dive into the microscopic world of atoms and electrons.
The Metal's Perspective
Copper
Copper is a classic metal, a brilliant conductor of electricity. In a metal, the outer electrons of the atoms are free to roam, forming a "sea of electrons." However, the atoms themselves are arranged in a lattice, and at room temperature, they vibrate vigorously due to thermal energy. These vibrations act like obstacles, scattering the flowing electrons and creating electrical resistance.
When we cool the copper down to , we are essentially draining thermal energy from the system. The lattice vibrations calm down significantly. With fewer obstacles in their path, the electrons can flow much more smoothly. Therefore, for a conductor like copper, as temperature decreases, its resistance decreases.
The Semiconductor's Perspective
Germanium
Germanium, on the other hand, is a semiconductor. Its behavior is governed by a completely different set of rules. At absolute zero, a semiconductor is a perfect insulator because all its electrons are tightly bound in covalent bonds. At room temperature, thermal energy is sufficient to break some of these bonds, exciting electrons into the conduction band and leaving behind "holes" in the valence band. These thermally generated electrons and holes are what allow germanium to conduct electricity.
When we cool the germanium down to , we are taking away the very thermal energy it relies on to generate charge carriers. The electrons fall back into their bonds, and the number of available charge carriers plummets exponentially. With fewer carriers available to transport charge, the material becomes much less conductive. Therefore, for a semiconductor like germanium, as temperature decreases, its resistance increases.
The Final Verdict
By understanding the fundamental differences in how metals and semiconductors conduct electricity, the answer becomes crystal clear. The cooling process calms the lattice vibrations in copper, making it a better conductor (resistance decreases). Simultaneously, it freezes the charge carriers in germanium, making it a worse conductor (resistance increases).
Similar Questions
LEVELBoard
Which of the following statements is not true ?
(A)
The resistance of intrinsic semiconductors decreases with increase of temperature.
(B)
Doping pure Si with trivalent impurities give -type semiconductors.
(C)
The majority carriers in -type semiconductors are holes.
(D)
A - junction can act as a semiconductor diode.
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When a potential difference is applied across, the current passing through
* Multiple Correct Options
(A)
an insulator at is zero
(B)
a semiconductor at is zero
(C)
a metal at is finite
(D)
a - diode at is finite, if it is reverse biased
LEVELJEE Main
Carbon, silicon and germanium have four valence electrons each. At room temperature, which one of the following statements is most appropriate? [AIEEE 2007]
(A)
The number of free conduction electrons is significant in C but small in Si and Ge
(B)
The number of free conduction electrons is negligibly small in all the three
(C)
The number of free electrons for conduction is significant in all the three
(D)
The number of free electrons for conduction is significant only in Si and Ge but small is C
LEVELBoard
At absolute zero, Si acts as
(A)
non-metal
(B)
metal
(C)
insulator
(D)
None of the above
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If the lattice constant of this semiconductor is decreased, then which of the following is correct?
(A)
All increase
(B)
and increase but decreases
(C)
and decrease but increases
(D)
All decrease
LEVELBoard
The energy band gap is maximum in
(A)
metals
(B)
superconductors
(C)
insulators
(D)
semiconductors
LEVELJEE Main
If the ratio of the concentration of electrons to that of holes in a semiconductor is and the ratio of currents is , then what is the ratio of their drift velocities?
(A)
(B)
(C)
(D)
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LEVELJEE Main
Mobility of electrons in a semiconductor is defined as the ratio of their drift velocity to the applied electric field. If for an -type semiconductor, the density of electrons is and their mobility is , then the resistivity of the semiconductor (since, it is an -type semiconductor contribution of holes is ignored) is close to
(A)
(B)
(C)
(D)
LEVELJEE Main
The electrical conductivity of a semiconductor increases when electro magnetic radiation of wavelength shorter than is incident on it. The band gap (in ) for the semiconductor is
(A)
(B)
(C)
(D)
LEVELJEE Main
The electrical conductivity of a semiconductor increases when electromagnetic radiation of wavelength shorter than , is incident on it. The band gap in (eV) for the semiconductor is
(A)
(B)
(C)
(D)
