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The Sigma Insight: Energy Bands in Solids and Semiconductors
The Magic of Semiconductors
Imagine a world where materials can decide whether they want to conduct electricity or not. Welcome to the fascinating realm of semiconductors! Unlike metals, which are always ready to let electrons flow, or insulators, which stubbornly block them, semiconductors have a conditional pass. This condition is governed by something called the Band Gap.
In the atomic structure of a semiconductor, electrons reside in the Valence Band. Above this band lies the Conduction Band, which is empty at absolute zero temperature. The gap between these two bands is the forbidden zone, the band gap (). For a semiconductor to conduct electricity, electrons must cross this gap. But they can't do it alone; they need a push.
The Photon's Push
This is where light comes into play. When electromagnetic radiation (light) falls on a semiconductor, it bombards the material with tiny packets of energy called photons. If a photon has enough energy—specifically, energy greater than or equal to the band gap ()—it can knock an electron from the valence band right into the conduction band.
Once in the conduction band, the electron is free to move, and voilà, the electrical conductivity of the semiconductor increases! This phenomenon is the core principle behind solar cells and light detectors.
Decoding the Problem
The problem states that conductivity increases when the wavelength of the incident light is shorter than . Why shorter? Because energy and wavelength have an inverse relationship, given by Planck's equation:
A shorter wavelength means higher energy. Therefore, the threshold wavelength, the absolute maximum wavelength that can just barely excite an electron, is . At this exact wavelength, the photon's energy perfectly matches the band gap energy ().
The Master Equation
To find the band gap, we need to calculate the energy of a photon with a wavelength of . While we could plug in the values of Planck's constant () and the speed of light () in standard SI units, there is a much faster, battle-tested shortcut for JEE and NEET:
(Note: Some textbooks use for higher precision, but is widely accepted and often makes calculations beautifully simple).
Final Calculation
First, let's convert our wavelength from nanometers to Angstroms. Since , we have:
Now, substitute this into our master equation:
Look at how perfectly those numbers align!
The band gap of the semiconductor is exactly . This means any photon with energy greater than (which corresponds to a wavelength shorter than ) will successfully increase the material's conductivity.
Similar Questions
LEVELJEE Main
The electrical conductivity of a semiconductor increases when electromagnetic radiation of wavelength shorter than , is incident on it. The band gap in (eV) for the semiconductor is
(A)
(B)
(C)
(D)
LEVELBoard
The energy band gap is maximum in
(A)
metals
(B)
superconductors
(C)
insulators
(D)
semiconductors
JEE Main 2019
LEVELJEE Main
Mobility of electrons in a semiconductor is defined as the ratio of their drift velocity to the applied electric field. If for an -type semiconductor, the density of electrons is and their mobility is , then the resistivity of the semiconductor (since, it is an -type semiconductor contribution of holes is ignored) is close to
(A)
(B)
(C)
(D)
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If the lattice constant of this semiconductor is decreased, then which of the following is correct?
(A)
All increase
(B)
and increase but decreases
(C)
and decrease but increases
(D)
All decrease
JEE Main 2021
LEVELJEE Main
In a semiconductor, the number density of intrinsic charge carriers at is . If the semiconductor is doped with impurity atom, the hole density increases to . The electron density in the doped semiconductor is ...... .
LEVELJEE Main
If the ratio of the concentration of electrons to that of holes in a semiconductor is and the ratio of currents is , then what is the ratio of their drift velocities?
(A)
(B)
(C)
(D)
LEVELBoard
Which of the following statements is not true ?
(A)
The resistance of intrinsic semiconductors decreases with increase of temperature.
(B)
Doping pure Si with trivalent impurities give -type semiconductors.
(C)
The majority carriers in -type semiconductors are holes.
(D)
A - junction can act as a semiconductor diode.
JEE Main 2021
LEVELJEE Main
For extrinsic semiconductors when doping level is increased,
(A)
Fermi level of p-type semiconductor will go upward and Fermi level of n-type semiconductors will go downward
(B)
Fermi level of p-type semiconductors will go downward and Fermi level of n-type semiconductor will go upward
(C)
Fermi level of p and n-type semiconductors will not be affected
(D)
Fermi level of both p-type and n-type semiconductors will go upward for K and downward for K, where is Fermi temperature
JEE Main 2021
LEVELJEE Main
Statement I: By doping silicon semiconductor with pentavalent material, the electrons density increases. Statement II: The n-type semiconductor has net negative charge. In the light of the above statements, choose the most appropriate answer from the options given below.
(A)
Statement I is true but statement II is false.
(B)
Statement I is false but statement II is true.
(C)
Both statement I and statement II are true.
(D)
Both statement I and statement II are false.
LEVELJEE Main
When a potential difference is applied across, the current passing through
* Multiple Correct Options
(A)
an insulator at is zero
(B)
a semiconductor at is zero
(C)
a metal at is finite
(D)
a - diode at is finite, if it is reverse biased
