Imagine a bustling microscopic city inside a drop of water. The citizens are aerobic bacteria, and their primary job is to clean up the city by eating organic waste. But just like us, these bacteria need oxygen to survive and do their heavy lifting. The more waste there is, the more bacteria show up to the feast, and the more oxygen they consume. This invisible hunger for oxygen is exactly what we measure when we talk about Biochemical Oxygen Demand (BOD).
Decoding the BOD Scale
Environmental chemists use BOD as a direct indicator of water pollution. It tells us how much dissolved oxygen (in parts per million, or ppm) is required by these microorganisms to break down the organic material present in a specific volume of water.
To make sense of these numbers, standard benchmarks have been established:
Clean Water: If the water is pristine, there is very little organic waste. The bacteria aren't working overtime, so the oxygen demand is low. Clean water typically has a BOD value of strictly less than 5 ppm.
Highly Polluted Water: When water is heavily contaminated with sewage or industrial runoff, it becomes an all-you-can-eat buffet for bacteria. Their population explodes, and they rapidly deplete the dissolved oxygen. Water is considered highly polluted when its BOD reaches or exceeds 17 ppm.
Analyzing the Given Samples
Let's apply this knowledge to the problem at hand. We are given two distinct water samples with specific BOD values.
Sample 1: The first sample has a BOD of 4 ppm.
Since 4 ppm<5 ppm, this falls perfectly into the safe zone. The oxygen demand is minimal, indicating that the water is free from significant organic contamination. Therefore, Sample 1 is clean.
Sample 2: The second sample has a BOD of 18 ppm.
Since 18 ppm>17 ppm, this triggers a massive red flag. The bacteria in this sample are consuming oxygen at an alarming rate to break down a heavy load of organic waste. Therefore, Sample 2 is highly polluted.
The Final Verdict
By simply comparing the given values against the standard environmental benchmarks, the conclusion is crystal clear. The first sample is clean, and the second sample is highly polluted. This perfectly matches option (d).
As a quick thought experiment: what happens if you encounter a water sample with a BOD of, say, 10 ppm? It doesn't fit into either extreme. In environmental chemistry, water with a BOD between 5 ppm and 17 ppm is classified as moderately polluted. Always keep these threshold values at your fingertips!