The Phenomenon of Simultaneous Decay
Imagine a radioactive nucleus that is highly unstable. Instead of following a single predictable path to stability, it has a choice. It can decay by emitting one type of particle to become a new element, or it can emit a completely different particle to become another element. This is known as simultaneous decay or branching decay.
When a substance decays through multiple independent paths simultaneously, the overall rate at which the parent nuclei disappear is simply the sum of the rates of the individual processes. Mathematically, the decay constants add up:
Calculating the Effective Decay Constant
In our problem, the radioactive material decays via two paths with half-lives T1=1400 yr and T2=700 yr. We know that the decay constant λ is related to the half-life by the equation λ=T1/2ln2.
Let's calculate the individual decay constants:
λ1=1400ln2 yr−1
λ2=700ln2 yr−1
Now, we find the effective decay constant by adding them together. To make the addition easier, we can use a common denominator of 1400:
λeff=1400ln2+14002ln2=14003ln2 yr−1
The Master Equation of Radioactive Decay
The fundamental law of radioactive decay states that the number of undecayed nuclei N(t) at any time t is given by:
We are asked to find the time t when exactly one-third of the original material remains. This means we set N(t)=3N0:
The initial amount N0 beautifully cancels out from both sides, leaving us with a pure exponential equation:
The Final Calculation
To bring the variable t down from the exponent, we take the natural logarithm (ln) on both sides. Remember the logarithmic property ln(1/x)=−lnx:
ln(31)=−λefft
−ln3=−λefft
ln3=λefft
Now, we substitute our expression for λeff back into the equation:
The problem provides the approximation ln3=1.1. We also use the standard approximation ln2≈0.693. Plugging these values in, we get:
Solving for t:
t=3×0.6931.1×1400=2.0791540≈740.74 yr
Rounding to the nearest option, we find that it takes approximately 740 years for the material to reduce to one-third of its initial amount.