The Ticking Clock of Radioactivity
Imagine a freshly prepared sample of a radioisotope as a room full of ticking clocks, each set to go off at a random time. While we can't predict when a specific clock will ring, we know exactly how the entire room behaves over time. This predictable behavior is governed by the law of radioactive decay.
In this problem, we are given a sample with a half-life of 1386 s and an initial activity of 103 disintegrations per second. Our goal is to find the percentage of nuclei that decay within the first 80 s.
Decoding the Decay Constant
The first step in any radioactivity problem is often finding the decay constant, λ. This constant tells us the probability of decay per unit time. It is intimately connected to the half-life, T1/2, through the relation:
We are given ln2=0.693 and T1/2=1386 s. Plugging these values in, we get:
This tiny number means that in any given second, a very small fraction of the nuclei will decay.
The Fraction of Decayed Nuclei
The number of active nuclei remaining at time t is given by the exponential decay law:
However, we are interested in the number of decayed nuclei, Nd. This is simply the initial number minus the remaining number:
To find the fraction of decayed nuclei, we divide by N0:
Fraction decayed=N0Nd=1−e−λt
The Power of Approximation
Now, we need to evaluate this fraction at t=80 s. Let's first calculate the exponent λt:
λt=(5×10−4 s−1)(80 s)=0.04
Since 0.04 is much less than 1, we can use a powerful mathematical tool: the Taylor series approximation. For very small values of x, the exponential function e−x can be approximated as 1−x.
Applying this to our fraction:
This brilliant shortcut saves us from calculating complex exponentials!
The Final Percentage
Using our approximation, the fraction of decayed nuclei is simply equal to λt, which is 0.04.
To express this as a percentage, we multiply by 100:
Percentage decayed=0.04×100=4%
And there we have it! In the first 80 s, exactly 4% of the initial nuclei will have decayed. Notice how the initial activity of 103 disintegrations per second was a red herring—we didn't need it at all to find the fraction!