The Setup
A Colorful Boundary
Imagine a beam of white light traveling through a dense glass medium and striking the boundary where it meets the air. White light is a beautiful mixture of all the colors of the rainbow—Violet, Indigo, Blue, Green, Yellow, Orange, and Red (VIBGYOR).
The problem gives us a fascinating clue: the green component of this white light just grazes the glass-air interface. In the language of physics, this means the angle of incidence i is exactly equal to the critical angle for green light, denoted as θcG.
But what happens to the other colors? Do they escape into the air, or are they trapped inside the glass? To answer this, we need to understand how the critical angle behaves for different colors.
The Master Equation
Cauchy's Formula
The critical angle θc for any medium is given by the relation:
where μ is the refractive index of the medium. But here is the catch: the refractive index is not a constant! It depends on the wavelength λ of the light. This relationship is beautifully captured by Cauchy's formula:
From this formula, we can draw a powerful conclusion: as the wavelength λ increases, the refractive index μ decreases. And if μ decreases, the value of sinθc increases, which means the critical angle θc itself increases.
In short: Longer wavelength ⟹ Smaller refractive index ⟹ Larger critical angle.
Analyzing the Spectrum
Now, let's look at our VIBGYOR spectrum. As we move from violet to red, the wavelength strictly increases:
λV<λI<λB<λG<λY<λO<λR
This means that Yellow, Orange, and Red have longer wavelengths than Green. Conversely, Violet, Indigo, and Blue have shorter wavelengths than Green.
The Great Escape
Yellow, Orange, and Red
Let's analyze the colors with longer wavelengths: Yellow, Orange, and Red. Since their wavelengths are greater than that of green (λ>λG), their critical angles must be greater than the critical angle of green (θc>θcG).
But remember, the angle of incidence i for the entire white light beam is fixed at θcG. Therefore, for Yellow, Orange, and Red, the angle of incidence is strictly less than their respective critical angles:
Because the angle of incidence is less than the critical angle, these colors will not suffer Total Internal Reflection. Instead, they will successfully refract and emerge into the air.
The Trapped Colors
Violet, Indigo, and Blue
What about Violet, Indigo, and Blue? Their wavelengths are shorter than that of green (λ<λG). Consequently, their critical angles are smaller than the critical angle of green (θc<θcG).
For these colors, our fixed angle of incidence i is now strictly greater than their critical angles:
When the angle of incidence exceeds the critical angle, the light cannot escape. Violet, Indigo, and Blue will undergo Total Internal Reflection (TIR) and bounce back into the glass.
Final Conclusion
The rays that successfully cross the boundary and emerge into the air are the ones with longer wavelengths. Therefore, the emerging ray in the air contains yellow, orange, and red. This is a stunning example of how dispersion and total internal reflection work hand-in-hand!