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Visualized Solution
The Sigma Insight: Kinetic Theory of Gases
Analyzing the Setup
Imagine a sealed glass tube lying flat on a table. Inside, a plug of mercury sits perfectly in the middle, trapping two equal columns of air on either side. Because the tube is horizontal, the mercury doesn't exert any net force on either air column, meaning the pressure is identical on both sides.
Since the tube is a rigid container, its total length is a strict constant. When we eventually tilt the tube, the lengths of the air columns will change to and , while the mercury remains long.
We can use this to find the initial length of each air column:
The Master Equation
Now, we tilt the tube so it makes an angle of with the vertical. This is equivalent to a angle with the horizontal. Gravity now pulls the mercury plug downwards along the incline, compressing the bottom air column and allowing the top one to expand.
Let the new pressure in the top column be and the bottom column be . The mercury plug is in equilibrium, so the forces acting on it must balance. The pressure from below pushes up, the pressure from above pushes down, and the component of the mercury's weight acts down the incline.
Balancing these forces gives us the pressure difference. If we express pressure directly in "cm of Hg", the pressure difference is simply the effective vertical height of the mercury column:
Since the temperature is held constant at , the trapped air undergoes an isothermal process. We can apply Boyle's Law () to both air columns to express and in terms of the initial pressure .
For the top column:
For the bottom column:
Final Calculation
We now substitute these expressions back into our master force balance equation:
Factoring out , we get:
Finally, isolating :
The initial pressure of the air in the tube was . A beautiful synthesis of fluid mechanics and thermodynamics!
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