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JEE Main 2021
LEVELJEE Main

Animated Solution for Physics - Thermodynamics: A cylindrical container of volume contains one mole of hydrogen and two moles of carbon dioxide. Assume the temperature of the mixture is . The pressure of the mixture of gases is [Take, gas constant ]

Select Answer:

Visualized Solution

  • Given:

  • Total number of moles in the mixture:

  • Using the ideal gas equation for the mixture:

  • Substituting the known values:

  • Calculating the numerator:

  • Final calculation:

  • The pressure of the mixture is .
  • This matches option (c).

The Sigma Insight: Kinetic Theory of Gases

Solution Diagram

Visualizing the Gas Mixture

Imagine you are looking at a sealed cylindrical container. Inside this container, a lively dance of molecules is taking place. We have a mixture of two different gases: one mole of hydrogen and two moles of carbon dioxide.
The container has a fixed volume of , and the entire system is kept at a warm temperature of .
Our goal is to figure out the total pressure exerted by these bouncing molecules on the walls of the container.

The Master Equation

When dealing with a mixture of non-reacting gases, we can rely on a beautiful principle known as Dalton's Law of Partial Pressures.
This law tells us that each gas acts as if it were alone in the container. The total pressure is simply the sum of the pressures each gas would exert individually.
Mathematically, this means we can treat the entire mixture as one single ideal gas. We just need to find the total number of moles!
So, the total moles is the sum of the moles of hydrogen and carbon dioxide:
Now, we bring in our master tool, the Ideal Gas Equation:
We want to find the pressure , so let's rearrange the equation:

Crunching the Numbers

With our equation ready, it's time to substitute the known values. We have , the gas constant , the temperature , and the volume .
Let's plug them in:
First, let's compute the numerator. Multiplying the moles, the gas constant, and the temperature:
Now, our expression looks much simpler:

The Final Reveal

To finish the calculation, we divide by .
Bringing the from the denominator to the numerator changes its sign, making it .
Now, we just divide by :
To match the options given in the question, we can rewrite this in standard scientific notation. By shifting the decimal point two places to the left, we increase the power of ten by two:
And there we have it! The total pressure of the gas mixture is , which perfectly matches option (c).

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