Sigma Percentile
JEE Advanced 2020
LEVELJEE Advanced

Animated Solution for Physics - Thermodynamics: A thermally isolated cylindrical closed vessel of height 8 m is kept vertically. It is divided into two equal parts by a diathermic (perfect thermal conductor) frictionless partition of mass 8.3 kg. Thus the partition is held initially at a distance of 4 m from the top, as shown in the schematic figure below. Each of the two parts of the vessel contains 0.1 mole of an ideal gas at temperature 300 K. The partition is now released and moves without any gas leaking from one part of the vessel to the other. When equilibrium is reached, the distance of the partition from the top (in m) will be ______. (take the acceleration due to gravity = 10 ms^{-2} and the universal gas constant = 8.3 J mol^{-1} K^{-1}).

Visualized Solution

Initial State Analysis

  • Initial volume of each part:
  • Initial temperature:
  • Moles in each part:

Releasing the Partition

  • Partition mass:
  • It moves down to a new equilibrium depth .
  • Final volumes: and

Mechanical Equilibrium

  • At equilibrium, forces on the partition balance:

Pressure Equations

  • Using Ideal Gas Law:

The Force Balance Equation

  • Substitute pressures into the equilibrium equation:

The Missing Link (Energy Conservation)

  • The entire cylinder is thermally isolated ().
  • Loss in Potential Energy = Gain in Internal Energy

The Setter's Trap

  • The problem states "ideal gas" but does not specify if it is monatomic or diatomic.
  • Without , cannot be found.
  • Assumption: What if the setter mistakenly assumed the process is isothermal ()?

Solving the Isothermal Case

  • Assume

Final Calculation

The Intended Answer

  • (since )
  • Note: The true answer depends on , making it a BONUS question.

The Sigma Insight: First Law of Thermodynamics

Solution Diagram

The Setup

A Deceptive Cylinder
Imagine you are standing in front of a massive, 8-meter-tall cylinder. It is perfectly thermally isolated from the outside world. Inside, a heavy 8.3 kg partition splits the cylinder perfectly in half.
Both the top and bottom compartments hold exactly 0.1 moles of an ideal gas at a comfortable 300 K.
Suddenly, the partition is released! Gravity takes over, pulling the heavy partition downward. It compresses the gas in the lower compartment while allowing the gas in the upper compartment to expand.
Eventually, the system settles into a new equilibrium state. Our mission is to find the new depth of this partition, let's call it .

The Physics of Equilibrium

When the partition finally comes to rest, it must be in perfect mechanical equilibrium.
This means the upward force exerted by the pressure of the bottom gas () must exactly balance the downward forces. These downward forces consist of the pressure from the top gas () and the gravitational weight of the partition itself ().
Mathematically, we can write this as:
Dividing the entire equation by the cross-sectional area , we get a clean relationship between the pressures:

The Temperature Conundrum

The partition is described as "diathermic," meaning it is a perfect conductor of heat.
Because heat can flow freely between the top and bottom compartments, they will eventually reach thermal equilibrium and share the exact same final temperature, .
Using the ideal gas law, , we can express the new pressures in terms of this final temperature and the new volumes. The top volume is and the bottom volume is .
Substituting these into our force balance equation gives:
Notice how beautifully the area cancels out from every term! We are left with:

The Missing Link

Energy Conservation
Here is where the plot thickens and the mystery begins.
The entire cylinder is thermally isolated, meaning no heat enters or leaves the system (). According to the First Law of Thermodynamics, the loss in gravitational potential energy of the falling partition must be entirely converted into the internal energy of the gas.
The partition falls from a depth of 4 meters to a new depth , so it loses of potential energy. The gas gains this energy, increasing its temperature from to .
We can write this energy conservation equation as:
Look closely at this equation. To find the final temperature , we desperately need the molar heat capacity at constant volume, .
But the problem simply states we have an "ideal gas." It never specifies whether the gas is monatomic, diatomic, or polyatomic! Without knowing the atomicity of the gas, is unknown, and the exact final temperature cannot be calculated.

The Examiner's Trap

This missing information is exactly why this question was awarded bonus marks in JEE Advanced 2020.
However, let's put ourselves in the shoes of the examiner. What if they made a conceptual error and mistakenly assumed the process was isothermal? What if they assumed the temperature remained constant at 300 K?
Let's test this hypothesis by plugging into our force balance equation.
We know , and the weight .
Substituting these values yields:

The Beautiful Cancellation

Look at how perfectly these numbers are designed!
The product of and is exactly . When we divide by , we get exactly . This is no coincidence; the numbers were hand-picked for this exact cancellation.
Simplifying the numerator gives . Cross-multiplying the denominator gives:
Expanding this out, we get:
Rearranging all terms to one side reveals a beautifully simple quadratic equation:

The Final Verdict

Factoring this quadratic equation is straightforward:
Since the depth must be a positive physical distance, we discard the negative root. This leaves us with:
This was undeniably the intended answer! The examiner crafted the numbers perfectly for an isothermal assumption.
However, physics is unforgiving. In reality, the temperature would absolutely increase due to the dissipated potential energy, making the true depth slightly different and heavily dependent on the specific type of gas.
A brilliant trap, a fascinating physical scenario, and a well-deserved bonus for the students!

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