Analyzing the Setup
Imagine you are looking at a tiny p-n junction diode. When it is reverse-biased, very little current flows through it. But suddenly, you shine a light on it, and the current spikes! What just happened? This is the magic of optoelectronic devices, specifically a photodiode. The light consists of tiny packets of energy called photons. When these photons hit the semiconductor material, they transfer their energy to the electrons sitting in the valence band.
If a photon has enough energy, it can kick an electron all the way across the forbidden energy gap (the band gap) into the conduction band. This creates a free electron and a hole, which are then swept away by the electric field, causing the reverse current to increase. The question tells us that this process happens for light with a wavelength of ≤621 nm. This maximum wavelength corresponds to the minimum energy required to just cross the band gap.
The Master Equation
To find the band gap energy Eg, we need to calculate the energy of a photon with a wavelength of λ=621 nm. The fundamental equation connecting the energy of a photon to its wavelength is:
where h is Planck's constant (6.63×10−34 J s) and c is the speed of light (3×108 m/s).
Substituting the Values
Let's plug in the raw numbers. Remember to convert the wavelength from nanometers to meters by multiplying by 10−9.
Eg=621×10−96.63×10−34×3×108 Joules
This gives us the energy in Joules. However, if you look at the options, they are all in electron-volts (eV). This is a classic trap! We must convert our answer.
Final Calculation
To convert Joules to electron-volts, we divide by the elementary charge e=1.6×10−19 C.
Eg=621×10−9×1.6×10−196.63×10−34×3×108 eV
Now, it's just a matter of careful arithmetic. Let's group the numbers and the powers of 10:
Eg=993.619.89×10−2810−26 eV
The band gap is approximately 2 eV, which perfectly matches option (a).
The Pro-Tip
In competitive exams like JEE, doing this long calculation can eat up precious minutes. Here is a golden shortcut:
Using this formula:
You instantly see that the answer is 2 eV without wrestling with massive powers of 10!