Animated Solution for Physics - Properties of Solids and Liquids: The ratio of surface tensions of mercury and water is given to be 7.5 while the ratio of their densities is 13.6. Their contact angles with glass are close to 135∘ and 0∘, respectively. It is observed that mercury gets depressed by an amount h in a capillary tube of radius r1, while water rises by the same amount h in a capillary tube of radius r2. The ratio (r1/r2), is then close to
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Visualized Solution
Capillary Action Setup
Water rises in a capillary tube of radius r2 by height h.
Mercury gets depressed in a capillary tube of radius r1 by the same amount h.
Jurin's Law
Capillary rise/depression is given by Jurin's Law:
h=ρgr2T∣cosθ∣
where T is surface tension, θ is contact angle, ρ is density, and r is radius.
Capillary action depends on the interplay between cohesive and adhesive forces.
What if the tube was tilted at an angle α? The vertical height h remains the same, but the length of the liquid column changes to l=cosαh.
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The Sigma Insight: Surface Tension and Capillary Action
Solution Diagram
Visualizing the Capillary Action
Imagine two capillary tubes dipped in different liquids. In the first one, water rises by a height h. In the second, mercury gets depressed by the exact same amount h. This beautiful symmetry in magnitudes is the key to unlocking this problem.
Water, with its strong adhesive forces to glass, forms a concave meniscus and climbs up the tube. Mercury, on the other hand, has strong cohesive forces, forming a convex meniscus and sinking below the surrounding liquid level. Despite these opposite behaviors, the problem states that the magnitude of their vertical displacement is identical.
The Master Equation
Jurin's Law
To find the relationship between these variables, we use Jurin's Law. The magnitude of capillary rise or depression h is given by:
h=ρgr2T∣cosθ∣
Here, T is the surface tension, θ is the contact angle, ρ is the density, and r is the radius of the capillary tube. We take the absolute value of cosθ because we are equating the physical magnitudes of the height, ignoring the directional sign that differentiates a rise from a depression.
Setting Up the Balance
Since the problem states that the rise of water equals the depression of mercury, we can set their equations equal to each other:
ρWgr22TWcos(0∘)=ρHggr12THg∣cos(135∘)∣
Notice how the 2 and g will cancel out beautifully from both sides. Now, let's rearrange the terms to isolate the ratio of the radii, r1/r2. We group the surface tension ratio, the density ratio, and the cosine ratio together. This makes our substitution step much cleaner:
r2r1=(TWTHg)×(ρHgρW)×(cos0∘∣cos135∘∣)
The Final Calculation
Let's plug in the values given in the problem. The surface tension ratio is 7.5. The density ratio of mercury to water is 13.6, so water to mercury is 1/13.6. And the absolute value of cos135∘ is 1/2.
r2r1=7.5×13.61×11/2
Now for the final calculation. We know that 2≈1.414. Multiplying 13.6 by 1.414 gives us about 19.23.
r2r1=19.237.5≈0.39
Dividing 7.5 by 19.23 yields approximately 0.39, which is very close to 0.4, or 2/5. And that's our final answer! The elegance of this problem lies in how neatly the ratios combine to give a simple fraction.