Introduction
The Magic of Capillary Action
Have you ever wondered how tall trees manage to transport water from their deep roots all the way to their highest leaves, defying gravity?
Or how a paper towel quickly drinks up a spill on your kitchen counter?
This beautiful phenomenon is known as capillary action, and it is governed by a delicate balance of molecular forces at the interface of solids, liquids, and gases.
In this article, we will dive deep into a classic JEE Advanced problem from 2018 that tests our conceptual understanding of capillary rise under varying physical conditions.
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The Physics of the Meniscus
Cohesive vs. Adhesive Forces
When a narrow glass tube—called a capillary tube—is dipped vertically into a liquid like water, we observe that the liquid rises inside the tube.
Why does this happen?
It all comes down to a molecular tug-of-war between two types of forces:
1. Adhesive Forces: The attractive forces between unlike molecules (e.g., water molecules and glass molecules).
2. Cohesive Forces: The attractive forces between like molecules (e.g., water molecules attracting each other).
For water and glass, the adhesive forces are significantly stronger than the cohesive forces.
As a result, water molecules "climb" up the glass wall, creating a curved, concave surface called a meniscus.
This curvature creates a pressure difference across the liquid-gas interface, pulling the liquid column upward until the upward force is perfectly balanced by the downward weight of the raised liquid column.
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Deriving Jurin's Law
The Force Balance
To analyze the problem quantitatively, let us derive the governing equation for capillary rise, known as Jurin's Law.
Let:
- r be the inner radius of the capillary tube.
- σ be the surface tension of the liquid.
- θ be the contact angle between the liquid and the tube wall.
- ρ be the density of the liquid.
- h be the height of the capillary rise.
The surface tension force acts along the perimeter of the contact line of length 2πr.
The vertical component of this force pulls the liquid upward:
This upward force is balanced by the weight of the liquid column of height h (ignoring the small mass of the meniscus):
W=Mass×g=(Volume×ρ)×g=(πr2h)ρg
At equilibrium, the upward force equals the downward weight:
Solving for h, we get the celebrated Jurin's Law:
Now, let us use this master equation to systematically evaluate each option of our problem.
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Deconstructing the Options
# 1
The Radius Factor: Why Narrower is Mightier
Let us look at Option (a): "For a given material of the capillary tube, h decreases with increase in r".
From Jurin's Law, if the liquid and tube material are kept constant, then σ, θ, ρ, and g are constants. This gives us a simple inverse relationship:
This means that as the inner radius r of the capillary tube increases, the height h of the liquid column must decrease.
Physically, a wider tube contains a heavier volume of water for the same perimeter, so the surface tension force cannot lift it as high.
Therefore, Option (a) is True.
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# 2
The Surface Tension Factor: The Molecular Tug-of-War
Let us look at Option (b): "For a given material of the capillary tube, h is independent of σ".
Looking back at our master equation:
We can clearly see that h is directly proportional to the surface tension σ:
If the surface tension of the liquid increases, the upward pulling force increases, causing the liquid to rise higher.
Thus, h is highly dependent on σ.
Therefore, Option (b) is False.
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# 3
The Gravity Factor: Capillary Rise in an Accelerating Lift
Let us look at Option (c): "If this experiment is performed in a lift going up with a constant acceleration, then h decreases".
When the entire setup is placed inside an elevator accelerating upward with a constant acceleration a, we must transition to the accelerated frame of reference.
In this non-inertial frame, a downward pseudo force of magnitude ma acts on the water column.
This effectively increases the acceleration due to gravity to an effective value:
Substituting geff into Jurin's Law, the new height h′ becomes:
Since the denominator has increased (g+a>g), the height of the capillary rise must decrease (h′<h).
Therefore, Option (c) is True.
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# 4
The Angle Factor: The Subtle Difference Between θ and cosθ
Finally, let us look at Option (d): "h is proportional to contact angle θ".
This is a classic trap designed to test mathematical precision. Jurin's Law states:
The height is proportional to the cosine of the contact angle, not the contact angle θ itself.
Since cosθ is a non-linear function of θ, doubling the angle θ does not double the height h.
Therefore, Option (d) is False.
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Conclusion
The Final Verdict
By systematically applying the principles of fluid mechanics and force balance, we have determined that:
- Option (a) is True.
- Option (b) is False.
- Option (c) is True.
- Option (d) is False.
Thus, the correct statements are (a) and (c).