Imagine you are standing in a freezing laboratory with a block of ice. This isn't just any block of ice; it has an unknown mass m grams, and it's currently chilling at a crisp −5∘C. Your mission is to supply exactly 420 J of heat to it and observe what happens.
The problem tells us that after supplying this heat, the ice warms up, starts melting, and eventually settles into an equilibrium state where exactly 1 g of it has turned into water. Our goal is to work backward like a thermal detective and find the original mass m. I know calorimetry problems can sometimes feel like a maze of units and formulas, but let's take a breath and break it down logically.
Analyzing the Setup
When you supply heat to a substance, it generally does one of two things: it either raises the temperature (sensible heat) or changes the phase (latent heat). It never does both at the exact same time for the same piece of mass.
In our scenario, the heat of 420 J goes on a two-part journey. First, it must warm up the entire block of ice from −5∘C to its melting point at 0∘C. Only after the whole block reaches 0∘C can the melting process begin. The second part of the journey is using whatever heat is left over to melt exactly 1 g of that ice into water.
The Master Equation
By the principle of calorimetry, the total heat supplied must equal the sum of the heat used in these two stages. We can write our master equation as:
Qtotal=miceciceΔT+mmeltedLf
Here is where we need to be hyper-vigilant about silly mistakes. The mass m is asked in grams, but the specific heat (cice=2100 J kg−1 ∘C−1) and latent heat (Lf=3.36×105 J kg−1) are given in SI units (per kilogram). We must convert our masses to kilograms by multiplying by 10−3.
Let's substitute the known values into our equation:
420=(m×10−3)×2100×(0−(−5))+(1×10−3)×3.36×105
Final Calculation
Let's solve this step-by-step. First, how much energy was consumed just to melt that 1 g of ice?
Qmelt=10−3×3.36×105=336 J
Out of our total budget of 420 J, a hefty 336 J was spent on melting. This means the remaining energy was used to warm up the ice initially.
Now we know that exactly 84 J of heat was used to raise the temperature of the unknown mass m from −5∘C to 0∘C. Let's plug this back into the sensible heat formula:
Finally, isolating m:
The original mass of the ice block was exactly 8 grams. Notice how beautifully the physics aligns when we track the energy step-by-step. Every joule is accounted for!