Sigma Percentile
JEE Advanced 2010
LEVELJEE Main

Animated Solution for Physics - Properties of Solids and Liquids: A piece of ice (heat capacity = and latent heat = ) of mass gram is at at atmospheric pressure. It is given 420 J of heat so that the ice starts melting. Finally when the ice-water mixture is in equilibrium, it is found that 1 g of ice has melted. Assuming there is no other heat exchange in the process, the value of is

Enter Numerical Value:

Visualized Solution

  • Initial state: Ice of mass at
  • Heat supplied:
  • Final state: Ice-water mixture at with ice melted.

  • Total heat supplied is used in two stages:
  • 1. Raising the temperature of the entire ice from to .
  • 2. Melting of ice at .

  • Heat to melt ice:

  • Heat available to raise temperature:

  • What if the heat supplied was ?
  • Would the entire of ice melt?

The Sigma Insight: Calorimetry

Solution Diagram
Imagine you are standing in a freezing laboratory with a block of ice. This isn't just any block of ice; it has an unknown mass grams, and it's currently chilling at a crisp . Your mission is to supply exactly of heat to it and observe what happens.
The problem tells us that after supplying this heat, the ice warms up, starts melting, and eventually settles into an equilibrium state where exactly of it has turned into water. Our goal is to work backward like a thermal detective and find the original mass . I know calorimetry problems can sometimes feel like a maze of units and formulas, but let's take a breath and break it down logically.

Analyzing the Setup

When you supply heat to a substance, it generally does one of two things: it either raises the temperature (sensible heat) or changes the phase (latent heat). It never does both at the exact same time for the same piece of mass.
In our scenario, the heat of goes on a two-part journey. First, it must warm up the entire block of ice from to its melting point at . Only after the whole block reaches can the melting process begin. The second part of the journey is using whatever heat is left over to melt exactly of that ice into water.

The Master Equation

By the principle of calorimetry, the total heat supplied must equal the sum of the heat used in these two stages. We can write our master equation as:
Here is where we need to be hyper-vigilant about silly mistakes. The mass is asked in grams, but the specific heat () and latent heat () are given in SI units (per kilogram). We must convert our masses to kilograms by multiplying by .
Let's substitute the known values into our equation:

Final Calculation

Let's solve this step-by-step. First, how much energy was consumed just to melt that of ice?
Out of our total budget of , a hefty was spent on melting. This means the remaining energy was used to warm up the ice initially.
Now we know that exactly of heat was used to raise the temperature of the unknown mass from to . Let's plug this back into the sensible heat formula:
Finally, isolating :
The original mass of the ice block was exactly 8 grams. Notice how beautifully the physics aligns when we track the energy step-by-step. Every joule is accounted for!

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