The behavior of paramagnetic materials in an external magnetic field is a fascinating interplay between order and chaos. On one hand, the external magnetic field tries to align the atomic dipoles, creating a net magnetisation. On the other hand, thermal agitation (temperature) acts as a disruptive force, causing the dipoles to jiggle around and lose their alignment.
Understanding Curie's Law
This tug-of-war is elegantly described by Curie's Law, which states that the magnetic susceptibility χm of a paramagnetic material is inversely proportional to its absolute temperature T. Mathematically, we write this as:
But what exactly is susceptibility? It is defined as the ratio of the induced magnetisation I to the magnetising field intensity H.
Furthermore, the magnetising field H is directly related to the external magnetic field B0 by the permeability of free space μ0:
The Master Proportionality
By substituting these definitions back into Curie's Law, we can uncover a direct relationship between the variables we actually care about: magnetisation, external field, and temperature.
Since μ0 is just a constant, we can absorb it into the proportionality, leaving us with a beautifully simple master equation:
This tells us exactly what we intuitively guessed: magnetisation increases if you crank up the magnetic field, but decreases if you heat up the material!
Setting Up the Ratio
Because we are dealing with the same paramagnetic sample under two different sets of conditions, we can set up a ratio to eliminate any proportionality constants.
I2I1=(B0)2(B0)1×T1T2
Notice how the temperatures are flipped (T2/T1) because of the inverse relationship. This is a common place where students make silly mistakes, so always double-check your indices!
Final Calculation
Now, we simply plug in the values provided in the problem. For the first state, we have I1=6 A/m, (B0)1=0.4 T, and T1=4 K. For the second state, (B0)2=0.3 T and T2=24 K.
Simplifying the fractions on the right side:
Finally, solving for I2:
And there we have it! The new magnetisation is 0.75 A/m. By understanding the physical principles behind the formula, the math becomes a breeze.