The Battle of Alignment
Paramagnetic materials are fascinating. Inside them, tiny atomic magnetic dipoles act like microscopic compass needles. When placed in an external magnetic field, these needles want to align perfectly with the field.
However, there is a chaotic villain in this story: temperature. Thermal energy causes the atoms to vibrate and jiggle, disrupting this perfect alignment. This tug-of-war between the magnetic field trying to align the dipoles and thermal agitation trying to randomize them is the essence of paramagnetism.
Curie's Law
The Mathematical Bridge
The French physicist Pierre Curie discovered a beautifully simple relationship to describe this behavior. He found that the magnetic susceptibility χ, which measures how easily a material gets magnetized, is inversely proportional to its absolute temperature T.
This is known as
Curie's Law:
χ∝T1
This means if you heat the material, its susceptibility drops. If you cool it down, it becomes easier to magnetize.
Decoding the Problem
In our specific problem, we are given a paramagnetic material with a known susceptibility at a specific temperature:
T1=350 K
χ1=2.8×10−4
We are asked to find the new susceptibility χ2 when the temperature is lowered to T2=300 K.
Notice that the problem also mentions the atomic density (1028 atoms/m3). This is a classic JEE distractor! The susceptibility χ is a macroscopic property that already accounts for the number of atoms per unit volume. We don't need this number to find the new susceptibility.
Setting Up the Ratio
Since
χ and
T are inversely proportional, we can set up a simple ratio:
χ1χ2=T2T1
Let's substitute our known values into this master equation:
2.8×10−4χ2=300350
The Final Calculation
Now, it's just a matter of careful algebra. First, let's simplify the temperature ratio:
300350=3035=67
Now, isolate
χ2:
χ2=2.8×10−4×67
Let's do the arithmetic:
χ2=619.6×10−4
χ2≈3.267×10−4
As expected, since we cooled the material from 350 K to 300 K, the thermal agitation decreased, and the magnetic susceptibility increased from 2.8×10−4 to 3.267×10−4. The physics perfectly matches the math!