The Bohr model of the hydrogen atom is a foundational concept in modern physics, bridging classical mechanics and quantum theory. In this problem, we will evaluate four statements regarding the properties of an electron in the nth orbit of a hydrogen atom. Let's break down the physics behind each option.
Analyzing the Radius of the Orbit
According to Bohr's postulates, the electrostatic force between the proton and the electron provides the necessary centripetal force for circular motion. Combined with the quantization of angular momentum, we can derive the radius of the
nth orbit:
rn=πme2Zϵ0h2n2
Notice the relationship between the radius
rn and the principal quantum number
n. The radius is directly proportional to the square of
n:
rn∝n2
This means that as the electron jumps to higher energy levels, the orbits become significantly larger, scaling quadratically. Therefore, the first statement is correct.
The Total Energy of the Electron
The total energy of the electron is the sum of its kinetic and potential energies. Using the derived radius, the total energy in the
nth orbit is given by:
En=−8ϵ02h2n2me4Z2
Here, the total energy is inversely proportional to the square of the principal quantum number
n:
En∝n21
The statement claims that the energy is inversely proportional to n, which is a common misconception. Because of the n2 dependence, the second statement is incorrect.
Quantization of Angular Momentum
Bohr's most revolutionary idea was the quantization of angular momentum. He proposed that an electron can only orbit in specific stable circular paths where its angular momentum
L is an integral multiple of
2πh:
L=2πnh
The option states that the angular momentum is an integral multiple of πh. This is missing the crucial factor of 2 in the denominator. Thus, the third statement is incorrect.
Potential vs
Kinetic Energy
Let's compare the magnitudes of the potential and kinetic energies of the electron. The potential energy
PE of the electron-proton system is:
PE=−4πϵ01re2
The kinetic energy
KE of the orbiting electron is:
KE=8πϵ01re2
Taking the absolute value (magnitude) of the potential energy, we get:
∣PE∣=4πϵ01re2
Comparing this with the kinetic energy, it is evident that:
∣PE∣=2×KE
Since the magnitude of the potential energy is exactly twice the kinetic energy, it is always greater than the kinetic energy in any orbit. Therefore, the fourth statement is correct.
Conclusion: The correct statements are (a) and (d).