The Cosmic Dance of the Electron
Imagine you are standing at the center of a hydrogen atom
Right beside you is the nucleus—a single, positively charged proton. Looking out into the vast emptiness of the atom, you see an electron zipping around you in a circular path. This is the nth Bohr orbit. But how fast is this electron moving? Does it speed up or slow down as it moves to orbits further away? Let's find out!
The Master Equation
Niels Bohr, in his brilliant model of the atom, gave us a way to calculate the exact velocity of an electron in any orbit
By balancing the electrostatic force of attraction with the required centripetal force, and applying his quantization of angular momentum (mvr=2πnh), we arrive at a beautiful expression for the velocity vn:
I know this equation might look a bit intimidating at first glance, but let's take a breath and break it down.
Decoding the Constants
Look closely at the terms in our master equation
For a given atom, like hydrogen, the atomic number Z is a constant (Z=1). The charge of the electron e, the permittivity of free space ε0, and Planck's constant h are all universal constants. They never change!
So, if we group all these constants together, we can rewrite our equation as:
The Final Verdict
This reveals a profound physical truth: the velocity of the electron vn is inversely proportional to the principal quantum number n.
What does this mean physically? As the electron jumps to higher orbits (larger n), it moves further away from the nucleus. The electrostatic pull from the nucleus weakens, so the electron doesn't need to travel as fast to maintain its orbit. It slows down! This elegant relationship perfectly matches option (b).
Always remember this inverse proportionality—it's a classic concept that frequently appears in JEE!