A Non-Standard Potential
In standard physics problems, we are incredibly used to the Coulomb potential, where V∝r1. But what happens when the universe throws a curveball and gives us a logarithmic potential?
In this fascinating problem, the electric potential between a proton and an electron is given by V=V0ln(r0r). Our mission is to find out how the radius of the n-th orbit, rn, depends on the principal quantum number n, assuming Bohr's model still holds true.
Finding the Force
The first step in analyzing any orbit is to understand the force keeping the particle in that orbit. In electrostatics, the electric field is the negative gradient of the potential. Therefore, the magnitude of the electrostatic force F on the electron is simply the charge e multiplied by the magnitude of the potential gradient.
Let's take the derivative of our given potential:
Using the chain rule, the derivative of ln(r/r0) is just 1/r. So, the force simplifies beautifully to:
The Centripetal Connection
For the electron to maintain a stable circular orbit, this electrostatic force must provide the exact centripetal force required. We equate the two:
Look closely at this equation! The radius r is present in the denominator on both sides. This means it cancels out completely!
This is a profound result. It tells us that for this specific logarithmic potential, the orbital velocity of the electron is a constant, completely independent of which orbit it is in!
Applying Bohr's Quantization
Now, we bring in the heavy machinery: Bohr's second postulate. Bohr stated that the angular momentum of an orbiting electron must be quantized in integral multiples of 2πh.
We already know that the velocity v is a constant. Let's substitute our expression for v into Bohr's condition:
Now, we simply rearrange the terms to isolate the radius of the n-th orbit, rn:
The Final Verdict
Take a step back and look at our final expression for rn. The mass m, the elementary charge e, the potential constant V0, and Planck's constant h are all fixed values. The only variable on the right side is the principal quantum number n.
Therefore, we can conclude that the radius of the n-th orbit is directly proportional to n.
This is a stark contrast to the standard hydrogen atom where rn∝n2. It beautifully demonstrates how changing the fundamental force law alters the quantum mechanical structure of the atom!