Analyzing the Setup
Imagine you are looking at a massive atom of Fermium (100Fm257). The question asks us to assume that this multi-electron atom strictly follows the Bohr model. Our goal is to find the radius of its outermost orbit and express it as a multiple of the Bohr radius (a0).
To do this, we first need to determine which orbit is the outermost one. In the Bohr-Bury scheme, the maximum number of electrons that can be accommodated in the mth shell is given by the formula 2m2.
Finding the Outermost Shell
Let's start filling the 100 electrons of Fermium into the shells:
- For m=1, capacity = 2(1)2=2 electrons.
- For m=2, capacity = 2(2)2=8 electrons.
- For m=3, capacity = 2(3)2=18 electrons.
- For m=4, capacity = 2(4)2=32 electrons.
If we sum up the electrons in the first four shells, we get:
2+8+18+32=60 electrons
Fermium has a total of 100 electrons. The remaining electrons are:
100−60=40 electrons
These 40 electrons will jump into the next available shell, which is the 5th shell (m=5). Therefore, the outermost orbit for this atom is m=5.
The Master Equation
Now, recall the formula for the radius of the
mth orbit in a hydrogen-like atom according to the Bohr model:
rm=Zm2a0
where Z is the atomic number and a0 is the Bohr radius (0.529 A˚).
Final Calculation
We know that for Fermium, the atomic number Z=100, and we just found that the outermost orbit is m=5. Let's substitute these values into our radius formula:
Simplifying the fraction, we get:
The question states that the radius is n times the Bohr radius (r5=na0). Comparing the two expressions, we can clearly see that:
Isn't it fascinating? Despite being in the 5th orbit, the massive nuclear charge of +100e pulls the electrons in so tightly that the orbit's radius is actually just one-fourth of the radius of a hydrogen atom's first orbit!