Sigma Percentile
JEE Main 2021
LEVELJEE Main

Animated Solution for Physics - Atoms and Nuclei: different wavelengths may be observed in the spectrum from a hydrogen sample if the atoms are exited to states with principal quantum number ? The value of is ........ .

Enter Numerical Value:

Visualized Solution

Energy Levels

  • Hydrogen sample excited to

Number of Spectral Lines

  • Total number of unique transitions:

Substitution

  • Substitute :

Calculation

Final Answer

Single Atom vs Sample

  • For a single atom:
  • Max lines =

The Sigma Insight: Bohr's Atomic Model and Energy Levels

Solution Diagram
The phenomenon of atomic emission spectra is one of the most beautiful validations of the Bohr model of the atom. When a sample of hydrogen gas is excited—perhaps by passing an electric discharge through it or heating it—the electrons in the atoms absorb energy and jump to higher, unstable energy levels.
But what goes up must come down. As these electrons return to lower energy states, they release the excess energy in the form of photons. Each specific jump corresponds to a photon of a specific energy, and therefore, a specific wavelength.

The Combinatorics of Spectral Lines

Imagine an electron sitting at the energy level. It doesn't have to jump all the way down to in a single leap. It could jump to , then to , and finally to . Each of these intermediate jumps emits a distinct wavelength of light.
Because we are dealing with a sample of hydrogen gas, we have billions of atoms. Statistically, every possible transition between the available energy levels will occur in some atom within the sample.
To find the total number of unique spectral lines, we simply need to find the number of ways to choose a starting level and an ending level from the available levels. This is a classic combinations problem: choosing 2 items from items, denoted as .
The formula for this is:

Calculating the Wavelengths

In our specific problem, the atoms are excited to the principal quantum number . We substitute this into our master equation:
Thus, the sample will emit 15 distinct wavelengths of light.

The "Single Atom" Trap

A classic trap in JEE and NEET exams is to change one word in the problem: asking for the maximum number of lines from a single isolated hydrogen atom instead of a sample.
A single atom only has one electron. That single electron can only take one specific path down to the ground state. The path that produces the maximum number of distinct lines is a cascade through every single intermediate level (e.g., ).
In this cascade, the number of jumps is simply . So, for a single atom excited to , the maximum number of lines would be . Always read the question carefully to see if you are dealing with a bulk sample or a single atom!

Similar Questions

JEE Main 2013
LEVELJEE Main

Hydrogen atom is excited from ground state to another state with principal quantum number equal to 4. Then, the number of spectral lines in the emission spectra will be

(A)
2
(B)
3
(C)
5
(D)
6
JEE Advanced 2016
LEVELJEE Main

A hydrogen atom in its ground state is irradiated by light of wavelength . Taking and the ground state energy of hydrogen atom as , the number of lines present in the emission spectrum is

JEE Main 2021
LEVELJEE Main

The first three spectral lines of H-atom in the Balmer series are given considering the Bohr atomic model, the wavelengths of first and third spectral lines are related by a factor of approximately . The value of to the nearest integer, is ……… .

JEE Main 2019
LEVELJEE Main

In a hydrogen like atom, when an electron jumps from the M-shell to the L-shell, the wavelength of emitted radiation is . If an electron jumps from N-shell to the L-shell, the wavelength of emitted radiation will be

(A)
(B)
(C)
(D)
JEE Advanced 1994
LEVELJEE Advanced

A hydrogen like atom (atomic number ) is in a higher excited state of quantum number . The excited atom can make a transition to the first excited state by successively emitting two photons of energy and respectively. Alternately, the atom from the same excited state can make a transition to the second excited state by successively emitting two photons of energies and respectively. Determine the values of and . (Ionization energy of H-atom )

JEE Main 2020
LEVELJEE Main

In a hydrogen atom, electron makes a transition from th level to the th level. If , the frequency of radiation emitted is proportional to

(A)
(B)
(C)
(D)
JEE Advanced 2005
LEVELJEE Advanced

If the wavelength of the line of Lyman series is equal to the de-Broglie wavelength of electron in initial orbit of a hydrogen like element (). Find the value of .

JEE Main 2013
LEVELJEE Main

In a hydrogen like atom electron make transition from an energy level with quantum number to another with quantum number . If , the frequency of radiation emitted is proportional to

(A)
(B)
(C)
(D)
JEE Main 2021
LEVELJEE Main

The wavelength of the photon emitted by a hydrogen atom when an electron makes a transition from to state is

(A)
121.8 nm
(B)
194.8 nm
(C)
490.7 nm
(D)
913.3 nm
JEE Main 2021
LEVELJEE Main

A particular hydrogen like ion emits radiation of frequency Hz when it makes transition from to . The frequency in Hz of radiation emitted in transition from to will be

(A)
(B)
(C)
(D)