Analyzing the Setup
Imagine a solid metal wire resting at a cool 0∘C. It has a specific mass M, an initial length L0, and an initial volume V0. Because density is simply how tightly packed this mass is, we can define its initial density as ρ0=V0M.
Now, we turn up the heat, bringing the wire to 10∘C. As thermal energy flows into the metal, the atoms vibrate more vigorously and push further apart. This causes the wire to expand in all directions—its length increases by ΔL and its volume increases by ΔV.
However, the total number of atoms hasn't changed. The mass M remains absolutely constant.
The Master Equation
Since the mass is constant, the expanding volume means the density must decrease. Let's look at the mathematical relationship. We know that:
ρ=VM
If we take the natural logarithm on both sides and differentiate to find the fractional changes, we get:
ρΔρ=MΔM−VΔV
Because the mass doesn't change,
ΔM=0. This simplifies our equation to:
ρΔρ=−VΔV
The negative sign perfectly captures our physical intuition: as volume goes up, density goes down. Since the question asks for the "percentage change" (which implies the magnitude of the change), we can focus on the absolute values:
Connecting Volume to Length
We need the fractional change in volume, but the problem only gives us the fractional change in length (0.02%). How do we bridge this gap?
For any isotropic material (a material that expands equally in all directions), the coefficient of volume expansion (
γ) is exactly three times the coefficient of linear expansion (
α).
γ=3α
We know the fundamental thermal expansion formulas:
VΔV=γΔT
LΔL=αΔT
By substituting
γ=3α into the volume equation, we reveal the hidden link:
VΔV=3αΔT=3(LΔL)
Final Calculation
We have successfully connected the change in density directly to the change in length!
To find the percentage change, we simply multiply both sides by 100:
Percentage change in density=3×(Percentage change in length)
The problem states that the percentage change in length is
0.02%. Substituting this value in:
Percentage change in density=3×0.02%=0.06%
The density changes by 0.06%. It's a small, subtle shift, but mathematically rigorous and physically profound!