This problem is a beautiful demonstration of how we can manipulate thermodynamic state variables to find exactly what we need. Let's embark on this journey step-by-step.
Analyzing the Setup
We are given a p−V diagram showing a gas expanding from state 1 to state 2. The curve is governed by a specific mathematical rule:
We are also handed a crucial piece of information regarding the volumes: the final volume is exactly twice the initial volume, meaning V2=2V1. Our ultimate goal is to find the ratio of their absolute temperatures, T1T2.
The Master Equation
The process equation relates pressure (p) and volume (V), but our target involves temperature (T). How do we bridge this gap? We call upon the fundamental law of ideal gases:
From this, we can isolate pressure:
This simple rearrangement is the key to unlocking the problem.
Transforming the Process Equation
Now, let's substitute our expression for pressure back into the given process equation. Replacing p, we get:
Let's simplify the powers of V. Dividing V1/2 by V1 gives us V−1/2. Since the number of moles (n) and the universal gas constant (R) are constants, we can absorb them into the constant on the right side, creating a new constant, let's call it C′.
This is a powerful realization! It tells us that for any two states in this process, the product of temperature and V−1/2 remains the same. Therefore:
Final Calculation
We are now perfectly positioned to find the required ratio. Let's rearrange our equation to isolate T1T2:
When negative exponents cross the fraction line, they become positive. This elegantly simplifies to:
Now, we bring in our initial condition, V2=2V1. Substituting this into our ratio:
The V1 terms cancel out flawlessly, leaving us with:
This matches option (b). The beauty of thermodynamics lies in these seamless transformations between state variables!