The Tale of Two Materials
When we heat up a material, its electrical properties can change drastically depending on its fundamental nature. In this problem, we are asked to compare the temperature dependence of resistance for two very different materials: Copper (Cu), a classic metal, and Silicon (Si), a standard semiconductor, specifically in the temperature range of 300 K to 400 K.
The Conductor's Plight
Copper
Imagine a crowded hallway where you (an electron) are trying to run from one end to the other. The people standing in the hallway represent the positive lattice ions. At lower temperatures, these people are relatively still, making it somewhat easy to navigate through them.
However, as the temperature increases, thermal energy causes these lattice ions to vibrate more vigorously. The people in the hallway start dancing around wildly! Naturally, you will bump into them more often. In physics terms, the relaxation time τ (the average time between collisions) decreases.
Since resistance R is inversely proportional to τ, the resistance of the metal increases. For a relatively small temperature range like 300 K to 400 K, this increase is well approximated by a linear relationship:
RT=R0(1+αΔT)
Thus, Copper exhibits a linear increase in resistance.
The Semiconductor's Awakening
Silicon
Now, let's look at Silicon. At absolute zero, an intrinsic (undoped) semiconductor behaves like a perfect insulator because all its electrons are tightly bound in the valence band. There is an energy gap, Eg, that they must cross to reach the conduction band and become free to move.
As we increase the temperature to 300 K and beyond, thermal energy acts like a key, unlocking electrons and promoting them across the bandgap. The number density of these free charge carriers, n, follows an exponential Boltzmann distribution:
n∝e−2kBTEg
Because the number of available charge carriers explodes exponentially with temperature, the material becomes vastly more conductive. Even though the lattice ions are vibrating more (just like in Copper), this effect is completely overwhelmed by the sheer exponential influx of new charge carriers.
Therefore, the resistivity ρ, and consequently the resistance R, drops exponentially:
R∝e2kBTEg
Thus, Silicon exhibits an exponential decrease in resistance.
The Final Verdict
Comparing our findings, Copper's resistance increases linearly, while Silicon's resistance decreases exponentially. This perfectly aligns with the physical models of metallic conduction and intrinsic semiconductor excitation.