The Setup
A Sphere in the Spotlight
Imagine a perfectly smooth silver sphere, suspended by an insulating thread in the vast emptiness of free space. We shine a continuous beam of ultraviolet light, with a wavelength of 200 nm, directly onto it. What happens next is a beautiful interplay between quantum mechanics and classical electrostatics.
As the high-energy UV photons strike the silver surface, they transfer their energy to the electrons. If a photon's energy is greater than the work function of silver (4.7 eV), it knocks an electron completely out of the metal. This is the famous photoelectric effect.
The Electrostatic Twist
But here is where the story gets interesting. Every time an electron escapes, it takes a negative charge with it. Because the sphere is isolated in space, it cannot replenish these lost electrons. Consequently, the silver sphere begins to acquire a net positive charge.
As more and more electrons are ejected, this positive charge grows. According to the laws of electrostatics, a positively charged sphere creates an electric potential around it. This potential acts like an invisible gravitational well, pulling the negatively charged escaping electrons back towards the sphere.
The Tipping Point
Initially, the most energetic photoelectrons have enough kinetic energy to escape this potential well. However, as the sphere's positive charge increases, the potential well deepens. Eventually, a critical point is reached: the positive potential becomes so strong that even the fastest, most energetic photoelectrons are pulled back before they can escape to infinity.
At this exact moment, the net emission of electrons completely stops. The potential of the sphere has reached a value equal to the stopping potential (V0) of the photoelectrons.
The Master Equation
To find this stopping potential, we turn to Einstein's photoelectric equation:
We can calculate the energy of the incident photons using the handy shortcut hc≈1240 eV\cdotnm:
Subtracting the work function of silver, we find the maximum kinetic energy of the ejected electrons:
Kmax=6.2 eV−4.7 eV=1.5 eV
This means the stopping potential V0 is exactly 1.5 V.
The Final Calculation
Now we know that the emission stops when the sphere's surface potential reaches 1.5 V. From classical electrostatics, the potential V of a conducting sphere of radius r carrying a total charge q is:
Since the total charge q is simply the number of emitted electrons n multiplied by the elementary charge e, we can write:
Let's plug in the values we know:
- V0=1.5 V
- 4πε01=9×109 N\cdotm2/C2
- e=1.6×10−19 C
- r=1 cm=10−2 m
1.5=10−2(9×109)⋅n⋅(1.6×10−19)
Simplifying the right side:
Solving for n:
n=14.4×10−81.5=14415×108≈1.04×107
The problem states that the maximum number of photoelectrons emitted is A×10Z. Comparing our result 1.04×107 with this format, we can clearly see that Z=7.