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JEE Main 2021
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Animated Solution for Chemistry - Organic Chemistry: Orlon fibres are made up of

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Visualized Solution

  • The monomer of Orlon is Acrylonitrile.
  • Chemical formula:

  • Acrylonitrile undergoes addition polymerisation.
  • The double bond breaks to form single bonds, linking monomers together.

  • The resulting polymer is Polyacrylonitrile (PAN).
  • Commercial name: Orlon or Acrilan.

  • Orlon = Polyacrylonitrile
  • Correct Option is (a).

The Sigma Insight: Polymers

Solution Diagram

The Magic of Synthetic Wool

Have you ever wrapped yourself in a warm, cozy sweater on a chilly winter evening and wondered what it is made of? While natural wool has been used for centuries, modern chemistry has given us a brilliant synthetic alternative: Orlon.
Orlon is a synthetic acrylic fiber that perfectly mimics the warmth and softness of natural wool, but with added benefits. It is lightweight, highly resistant to moths, and does not degrade easily under sunlight or harsh chemicals. But what exactly is this magical material made of? To answer that, we need to dive into the microscopic world of polymers and look at the building blocks that create Orlon.

The Building Block

Acrylonitrile
Every giant polymer chain starts with a single, repeating unit known as a monomer. For Orlon, this fundamental building block is a molecule called Acrylonitrile (also known as vinyl cyanide).
The chemical structure of acrylonitrile is quite simple yet highly reactive: ``.
If you look closely at this molecule, you will notice two critical features. First, there is a carbon-carbon double bond (``). This double bond is the engine of the polymerization process; it is highly reactive and ready to break open to form new connections. Second, there is a cyanide group (``) attached to one of the carbon atoms. This highly electronegative group is what gives the final polymer its incredible strength and resistance, as it creates strong dipole-dipole interactions between adjacent polymer chains.

The Polymerization Journey

So, how do we go from a simple liquid monomer to a tough, wool-like fiber? The answer lies in a chemical process called addition polymerization.
Imagine a massive reaction vessel filled with millions of acrylonitrile molecules. When a catalyst (often a peroxide initiator) is introduced, it triggers a chain reaction. The reactive carbon-carbon double bond in the acrylonitrile molecule breaks open.
It is as if each molecule suddenly reaches out its arms to grab the hands of the molecules next to it. Because the molecules simply add together without the loss of any small atoms or molecules (like water or ammonia), this is classified as an addition reaction.
This continuous linking creates a massive, long-chain macromolecule. The resulting polymer is scientifically named Polyacrylonitrile, often abbreviated as PAN.

Why Orlon?

While chemists refer to this long-chain molecule as Polyacrylonitrile, the textile and commercial industries needed a catchier name. Thus, the trade name Orlon was born. (You might also hear it referred to as Acrilan in some markets).
Therefore, when a question asks what Orlon fibers are made of, the answer is a direct translation of its scientific identity. Orlon is simply the commercial name for polyacrylonitrile.
Understanding the connection between commercial trade names and their scientific chemical structures is a crucial skill in organic chemistry. It not only helps you ace memory-based questions in exams like JEE and NEET but also gives you a deeper appreciation for the materials that make up our everyday world!

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