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JEE Main 2021
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Animated Solution for Chemistry - Organic Chemistry: The number of nitrogen atoms in a semicarbazone molecule of acetone is .......

Enter Numerical Value:

Visualized Solution

\text{Structure of Acetone Semicarbazone}

  • \text{Acetone reacts with semicarbazide to form acetone semicarbazone.}

\text{Identifying Nitrogen Atoms}

  • \text{Chemical Formula: } (\text{CH}_3)_2\text{C=N-NH-CO-NH}_2

\text{Counting the Nitrogen Atoms}

  • \text{Total Nitrogen Atoms } = 1 (\text{from NH}_2) + 1 (\text{from NH}) + 1 (\text{from N=C}) = 3

\text{Final Answer}

  • \text{Number of Nitrogen atoms } = 3

The Sigma Insight: Carbonyl Compounds

Solution Diagram

The Reaction Setup

Imagine you are in an organic chemistry lab, and you mix acetone with a reagent called semicarbazide. What happens next is a classic condensation reaction. The carbonyl oxygen of the acetone molecule teams up with two hydrogen atoms from the semicarbazide to form a water molecule, which is eliminated.
What is left behind is a beautifully crystalline solid known as acetone semicarbazone. These types of derivatives are incredibly useful for chemists because their sharp melting points help in identifying unknown aldehydes and ketones.

Analyzing the Structure

To answer our question, we don't need to do any complex math; we just need to look closely at the structure of the molecule we've formed. The chemical formula for acetone semicarbazone is .
Let's take a walk through this molecule from left to right. On the far left, we have the two methyl groups from the original acetone molecule attached to a carbon atom. This carbon is double-bonded to a nitrogen atom. That's our first nitrogen!

The Final Count

Moving further right along the chain, this first nitrogen is single-bonded to another nitrogen atom, which is part of an group. That's our second nitrogen.
Finally, after passing through the carbonyl carbon (), we reach the end of the molecule, which terminates in an group. This gives us our third and final nitrogen atom.
So, if we tally them all up: one from the imine-like double bond, one from the secondary amine linkage, and one from the terminal amide group. The total number of nitrogen atoms in a single molecule of acetone semicarbazone is exactly 3.

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