The study of metallurgy begins with a fundamental understanding of ores—the naturally occurring solid materials from which a metal or valuable mineral can be profitably extracted. In this problem, we are presented with a classic matching challenge: pairing a list of well-known ores with their corresponding primary metals.
The Matching Challenge
We are given four ores in Column A: Siderite, Kaolinite, Malachite, and Calamine. In Column B, we have the metals: Zinc, Copper, Iron, and Aluminium. To solve this, we must recall the chemical composition of each ore. Let's break them down one by one.
Decoding the Ores
1. Siderite
Siderite is a widespread iron mineral. It is a carbonate ore with the chemical formula FeCO3. Because it contains iron, it is an important source for iron extraction, although less common than oxides like haematite or magnetite.
Therefore, Siderite (A) matches with Iron (R).
2. Kaolinite
Kaolinite is a clay mineral, part of the group of industrial minerals. It is a layered silicate mineral, specifically an aluminosilicate, with the chemical formula Al2Si2(OH)4O5. It is a primary ore of aluminium.
Therefore, Kaolinite (B) matches with Aluminium (S).
3. Malachite
Malachite is a beautiful, green copper carbonate hydroxide mineral. Its striking color has made it historically significant as a pigment and a gemstone. Its chemical formula is CuCO3⋅Cu(OH)2. As the formula suggests, it is a rich source of copper.
Therefore, Malachite (C) matches with Copper (Q).
4. Calamine
Calamine is a historic name for an ore of zinc. It primarily consists of zinc carbonate, with the chemical formula ZnCO3. It is often found in association with smithsonite and is a key source for zinc extraction.
Therefore, Calamine (D) matches with Zinc (P).
The Final Alignment
By systematically identifying the chemical formula of each ore, we have successfully mapped them to their respective metals:
- A → R (Siderite → Iron)
- B → S (Kaolinite → Aluminium)
- C → Q (Malachite → Copper)
- D → P (Calamine → Zinc)
This sequence perfectly aligns with option (d). Remembering these chemical formulas is not just about solving matching questions; it provides deep insight into the thermodynamic and electrochemical principles required to extract these metals efficiently!