Imagine you are a detective, and the p−V diagram is your crime scene. Every line, every point holds a clue about what the gas is experiencing. Is it heating up? Is it doing work? Is it absorbing heat? To crack this case, we need our master key: the First Law of Thermodynamics.
The First Law
Our Guiding Light
The First Law is beautifully simple: ΔQ=ΔU+ΔW. It tells us that the heat ΔQ supplied to a gas goes into two things: changing its internal energy ΔU and doing work ΔW.
To find the sign of work ΔW, we just look at the volume. If the gas expands, it pushes against its surroundings, doing positive work. If it's compressed, work is negative. If the volume doesn't change, work is zero.
For the internal energy ΔU, we look at the temperature. For an ideal gas, pV=nRT. This means the temperature is directly proportional to the product of pressure and volume (pV). If pV increases, the gas is heating up, and ΔU is positive. If pV decreases, it's cooling down, and ΔU is negative.
Analyzing the Isochoric Paths
Let's start with the vertical paths, where the volume is constant. These are called isochoric processes.
Process J→K:
The gas goes from a pressure of 30 to 10 while the volume stays locked at 10 m3. Because the volume doesn't budge, the gas does no work: ΔW=0.
What about the temperature? At J, pV=30×10=300. At K, pV=10×10=100. The product pV has plummeted, meaning the gas has cooled down significantly. Therefore, ΔU<0.
Plugging this into our First Law: ΔQ=negative+0, which means ΔQ<0. The gas is losing heat! This matches option (s).
Process L→M:
This is the other vertical path. The volume is constant at 20 m3, so again, ΔW=0.
This time, the pressure increases from 10 to 20. The product pV jumps from 200 (at L) to 400 (at M). The gas is heating up, so ΔU>0.
Our First Law tells us: ΔQ=positive+0, meaning ΔQ>0. The gas is absorbing heat. This matches option (p).
The Isobaric Expansion
Now let's look at the horizontal path, Process K→L.
Here, the pressure is constant at 10, but the volume expands from 10 to 20 m3. Because the gas is expanding, it's doing positive work: ΔW>0.
Let's check the temperature. The product pV goes from 100 (at K) to 200 (at L). The temperature is rising, so ΔU>0.
With both work and internal energy being positive, their sum must be positive: ΔQ>0. The gas is absorbing heat while doing work. This matches options (p) and (r).
The Final Compression
Finally, we have the slanted path, Process M→J.
The volume is being crushed from 20 down to 10 m3. Because it's a compression, the work done is negative: ΔW<0.
What about the internal energy? At M, pV=400. At J, pV=300. The product pV is decreasing, which means the gas is cooling down, so ΔU<0.
Both terms in our First Law are negative, so their sum must be negative: ΔQ<0. The gas is losing heat while being compressed. This matches options (q) and (s).
Bringing It All Together
By breaking down the cycle into individual processes and applying the First Law, we've solved the mystery. We didn't need complex integrals or messy algebra—just a solid understanding of how pressure, volume, and temperature interact. This is the true elegance of thermodynamics!