Sigma Percentile
LEVELJEE Main

Animated Solution for Physics - Thermodynamics: Match the following for the given process

List-I

(P)
Process
(Q)
Process
(R)
Process
(S)
Process

List-II

(1)
(2)
(3)
(4)

Select Matching Pairs:

PMatches
QMatches
RMatches
SMatches

Visualized Solution

The Sigma Insight: First Law of Thermodynamics

Solution Diagram
Imagine you are a detective, and the diagram is your crime scene. Every line, every point holds a clue about what the gas is experiencing. Is it heating up? Is it doing work? Is it absorbing heat? To crack this case, we need our master key: the First Law of Thermodynamics.

The First Law

Our Guiding Light
The First Law is beautifully simple: . It tells us that the heat supplied to a gas goes into two things: changing its internal energy and doing work .
To find the sign of work , we just look at the volume. If the gas expands, it pushes against its surroundings, doing positive work. If it's compressed, work is negative. If the volume doesn't change, work is zero.
For the internal energy , we look at the temperature. For an ideal gas, . This means the temperature is directly proportional to the product of pressure and volume (). If increases, the gas is heating up, and is positive. If decreases, it's cooling down, and is negative.

Analyzing the Isochoric Paths

Let's start with the vertical paths, where the volume is constant. These are called isochoric processes.
Process : The gas goes from a pressure of to while the volume stays locked at . Because the volume doesn't budge, the gas does no work: . What about the temperature? At , . At , . The product has plummeted, meaning the gas has cooled down significantly. Therefore, . Plugging this into our First Law: , which means . The gas is losing heat! This matches option (s).
Process : This is the other vertical path. The volume is constant at , so again, . This time, the pressure increases from to . The product jumps from (at ) to (at ). The gas is heating up, so . Our First Law tells us: , meaning . The gas is absorbing heat. This matches option (p).

The Isobaric Expansion

Now let's look at the horizontal path, Process . Here, the pressure is constant at , but the volume expands from to . Because the gas is expanding, it's doing positive work: . Let's check the temperature. The product goes from (at ) to (at ). The temperature is rising, so . With both work and internal energy being positive, their sum must be positive: . The gas is absorbing heat while doing work. This matches options (p) and (r).

The Final Compression

Finally, we have the slanted path, Process . The volume is being crushed from down to . Because it's a compression, the work done is negative: . What about the internal energy? At , . At , . The product is decreasing, which means the gas is cooling down, so . Both terms in our First Law are negative, so their sum must be negative: . The gas is losing heat while being compressed. This matches options (q) and (s).

Bringing It All Together

By breaking down the cycle into individual processes and applying the First Law, we've solved the mystery. We didn't need complex integrals or messy algebra—just a solid understanding of how pressure, volume, and temperature interact. This is the true elegance of thermodynamics!

Similar Questions

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Comprehension Passage

In a thermodynamics process on an ideal monatomic gas, the infinitesimal heat absorbed by the gas is given by , where is temperature of the system and is the infinitesimal change in a thermodynamic quantity of the system. For a mole of monatomic ideal gas . Here, is gas constant, is volume of gas, and are constants. The List-I below gives some quantities involved in a process and List-II gives some possible values of these quantities. List-I (I) Work done by the system in process (II) Change in internal energy in process (III) Heat absorbed by the system in process (IV) Heat absorbed by the system in process List-II (P) (Q) (R) (S) (T) (U)
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If the process carried out on one mole of monatomic ideal gas is as shown in figure in the PV-diagram with , the correct match is,

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Question 2:

If the process on one mole of monatomic ideal gas is an shown is as shown in the TV-diagram with , the correct match is

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