Animated Solution for Chemistry - s and p-Block Elements: Match the following compounds (Column -I) with their uses (Columns -II).
Column -I(I) Ca(OH)2(II) NaCl(III) CaSO4⋅21H2O(IV) CaCO3Column - II(A) Casts of statues(B) White wash(C) Antacid(D) Washing soda preparation
Select Answer:
Visualized Solution
Ca(OH)2
Ca(OH)2 is commonly known as slaked lime.
It is widely used for white washing of walls.
It reacts slowly with CO2 in air to form a thin shining layer of CaCO3.
NaCl
NaCl is a key raw material in the Solvay process for manufacturing washing soda (Na2CO3).
NH3+H2O+CO2→NH4HCO3
NH4HCO3+NaCl→NaHCO3↓+NH4Cl
2NaHCO3ΔNa2CO3+H2O+CO2
CaSO4⋅21H2O
CaSO4⋅21H2O is Plaster of Paris (POP).
On mixing with water, it sets into a hard mass of gypsum (CaSO4⋅2H2O).
It is used for making casts of statues, toys, and in bone fractures.
CaCO3
CaCO3 is a mild base.
It neutralizes excess stomach acid (HCl).
CaCO3+2HCl→CaCl2+H2O+CO2
Hence, it is used as an antacid.
\text{Final Match}
(I) Ca(OH)2→ (B) White wash
(II) NaCl→ (D) Washing soda preparation
(III) CaSO4⋅21H2O→ (A) Casts of statues
(IV) CaCO3→ (C) Antacid
Correct Option: (b)
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The Sigma Insight: Alkaline Metals
The s-block elements and their compounds are not just abstract chemicals in a textbook; they are deeply woven into our everyday lives. This question is a beautiful reminder of how chemistry operates all around us, from the walls of our houses to the medicines we take. Let's break down the uses of each of these fascinating compounds.
The Magic of Slaked Lime
First on our list is calcium hydroxide, Ca(OH)2, commonly known as slaked lime. If you've ever seen a house being painted with a traditional white wash, you've seen this compound in action.
When slaked lime is applied to walls, it doesn't just dry; it undergoes a slow chemical reaction. It absorbs carbon dioxide (CO2) from the air to form a thin, hard, and shiny layer of calcium carbonate (CaCO3). This is what gives white-washed walls their characteristic bright finish. Therefore, Ca(OH)2 perfectly matches with white wash.
The Hidden Role of Table Salt
Next, we have sodium chloride, NaCl. While we all know it as table salt, its industrial importance is massive. It is a primary raw material in the Solvay process, which is used to manufacture washing soda (Na2CO3).
In the Solvay process, ammonia, water, and carbon dioxide react to form ammonium bicarbonate. This intermediate then reacts with our NaCl to precipitate sodium bicarbonate (NaHCO3). Finally, heating this sodium bicarbonate yields the desired washing soda.
2NaHCO3ΔNa2CO3+H2O+CO2
Thus, NaCl is intrinsically linked to washing soda preparation.
The Art of Plaster of Paris
Moving on to calcium sulphate hemihydrate, CaSO4⋅21H2O. This compound is universally famous as Plaster of Paris (POP).
The magic of POP lies in its hydration. When mixed with an appropriate amount of water, it rapidly sets into a hard, solid mass known as gypsum (CaSO4⋅2H2O). Because it forms a workable paste before hardening, it is the perfect material for molding. It is extensively used for making casts of statues, decorative ceilings, and even for immobilizing fractured bones in orthopedics.
Relief from Acidity
Finally, we look at calcium carbonate, CaCO3. This naturally occurring mineral (found in limestone and marble) is mildly basic.
When you suffer from indigestion or acidity, your stomach has overproduced hydrochloric acid (HCl). Calcium carbonate acts as an effective antacid. It reacts with the excess stomach acid, neutralizing it and releasing carbon dioxide gas, which provides quick relief.
CaCO3+2HCl→CaCl2+H2O+CO2
Hence, CaCO3 is a classic antacid.
The Final Verdict
By connecting the dots:
Ca(OH)2→ White wash
NaCl→ Washing soda preparation
CaSO4⋅21H2O→ Casts of statues
CaCO3→ Antacid
This sequence perfectly matches option (b). Chemistry is truly everywhere!