The Roadmap of Stoichiometry
Imagine you are planning a massive road trip. You wouldn't just start driving without a map, right? In chemistry, our map is the balanced chemical equation. It tells us exactly how much of each ingredient we need and how much product we will get.
For our problem, we are given the combustion reaction of a giant organic molecule:
2C57H110O6(s)+163O2(g)⟶114CO2(g)+110H2O(l)
Our goal is to find out how much water is produced from a specific amount of the reactant. To do this, we first need to extract the core relationship from our "map". By looking at the stoichiometric coefficients, we can see that 2 moles of our complex organic reactant will produce exactly 110 moles of water. This molar ratio is the fundamental bridge connecting the two substances.
Decoding the Molar Masses
Now, the problem gives us the amount of reactant in grams, not moles. So, we need to translate our molar map into a mass map. This means calculating the molar masses.
Let's start with our giant molecule,
C57H110O6. I know this looks terrifying, but let's take a breath and break it down. Carbon has an atomic mass of
12, hydrogen is
1, and oxygen is
16.
Molar Mass=(12×57)+(1×110)+(16×6)
Molar Mass=684+110+96=890 g/mol
Since our balanced equation uses
2 moles of this reactant, the total mass involved is:
Total Mass of Reactant=2×890=1780 g
Next, we do the same for water (
H2O). The molar mass of water is a familiar
18 g/mol. For
110 moles, the total mass is:
Total Mass of Water=110×18=1980 g
The Elegance of the Unitary Method
We have successfully translated our map! We now know that 1780 g of the reactant produces 1980 g of water.
But the question asks about a specific scenario: what happens if we only have 445 g of the reactant? This is where the simple unitary method comes to our rescue.
If
1780 g yields
1980 g, then
1 g yields
17801980 g.
Therefore,
445 g will yield:
Mass of H2O=17801980×445
Before you start doing long division, pause and look at the numbers. JEE problems often have hidden mathematical elegance. Notice that
1780 is exactly four times
445!
1780=4×445
This beautiful cancellation makes our calculation incredibly simple:
Mass of H2O=41980=495 g
And there we have it! By carefully following the stoichiometric map and keeping an eye out for mathematical shortcuts, we arrived at the final answer of 495 g.