The Setup
A Journey Through Mercury Vapour
Imagine you are observing a sealed chamber filled with mercury vapour.
We fire an electron into this chamber with an initial kinetic energy of 5.6 eV.
After traversing the vapour, the electron emerges on the other side, but its energy has dropped to just 0.7 eV.
The Collision
Energy Transfer in Action
So, where did the missing energy go?
According to the law of conservation of energy, it couldn't have just vanished.
During its journey, the electron collided with a mercury atom and transferred a specific chunk of its kinetic energy to it.
This absorbed energy causes the mercury atom to jump from its ground state to a higher, excited energy level.
We can easily calculate this absorbed energy by finding the difference between the electron's initial and final energies.
The Emission
Calculating the Wavelength
Now, this excited mercury atom is unstable and won't stay in that high-energy state forever.
It will eventually de-excite, dropping back down to the ground state.
As it drops, it releases the stored 4.9 eV of energy in the form of a photon.
The question asks for the minimum wavelength of the emitted photons.
Since wavelength is inversely proportional to energy, the minimum wavelength corresponds to the maximum energy transition.
This happens when the atom releases the entire 4.9 eV in a single, massive jump.
To find the wavelength, we use the classic Planck-Einstein relation:
To make our calculation lightning fast, we use the standard approximation hc≈1240 eV⋅nm.
Looking at our options, the closest value is 250 nm.
The Legacy
Proving Bohr Right
This isn't just any random calculation; this is the historic Franck-Hertz experiment!
Before this experiment, the idea that atoms had discrete, quantized energy levels was just a theoretical postulate in Bohr's model.
By showing that electrons only lose specific, quantized amounts of energy when colliding with atoms, Franck and Hertz provided the first direct experimental proof of quantum energy levels.
It is a beautiful demonstration of quantum mechanics in action!