Sigma Percentile
JEE Advanced 2021
LEVELJEE Main

Animated Solution for Physics - Thermodynamics: An ideal gas undergoes a four step cycle as shown in the P – V diagram below. During this cycle, heat is absorbed by the gas in

Select Answer:

Visualized Solution

The P-V Cycle

  • Four-step cyclic process of an ideal gas.
  • Goal: Identify steps where

First Law of Thermodynamics

  • Area under P-V curve

Process 1: Isobaric Expansion

  • Heat Absorbed

Process 2: Isochoric Pressure Drop

  • Heat Rejected

Process 3: Isobaric Compression

  • Heat Rejected

Process 4: Isochoric Pressure Rise

  • Heat Absorbed

Conclusion

  • Heat is absorbed in:
  • Step 1
  • Step 4

The Sigma Insight: First Law of Thermodynamics

Solution Diagram
The study of thermodynamics often feels like an intricate dance between heat, work, and internal energy. In this problem, we are presented with a classic rectangular cycle on a P-V diagram. Our objective is to determine exactly where the gas is absorbing heat from its surroundings.
To unlock the secrets of this cycle, we must rely on the First Law of Thermodynamics.

The Master Equation

The First Law of Thermodynamics is essentially the law of conservation of energy applied to thermal systems. It states:
Here, is the heat supplied to the gas, is the change in its internal energy, and is the work done by the gas.
For an ideal gas, the internal energy depends exclusively on its temperature. According to the ideal gas equation, , the temperature is directly proportional to the product of pressure and volume (). Therefore, if the product increases, the temperature rises, and is positive.
Work done, on the other hand, is geometrically represented as the area under the P-V curve. If the gas expands (volume increases), the work done is positive. If it is compressed, the work done is negative.

Analyzing Process 1

Isobaric Expansion
Let's look at the first step, labeled as process 1. The arrow points to the right, indicating that the volume is increasing while the pressure remains constant. This is an isobaric expansion.
Because the volume is increasing, the gas is doing work on its surroundings.
Simultaneously, since the pressure is constant and the volume is increasing, their product is increasing. This means the temperature of the gas is rising, leading to an increase in internal energy.
Plugging these into our master equation, a positive work and a positive change in internal energy guarantee that is positive. The gas is absorbing heat.

Analyzing Process 2

Isochoric Pressure Drop
Moving to process 2, the path goes straight down. The volume is perfectly constant, meaning the gas is neither expanding nor compressing. This is an isochoric process.
Since there is no change in volume, the area under the curve is zero.
However, the pressure is dropping. A decrease in pressure at a constant volume means the product is decreasing. The gas is cooling down, so its internal energy decreases.
With zero work and a negative change in internal energy, must be negative. The gas is rejecting heat.

Analyzing Process 3

Isobaric Compression
In process 3, the arrow points to the left. The gas is being compressed while the pressure is held constant.
Because the volume is decreasing, the work done by the gas is negative.
The product is also decreasing because the volume is shrinking at a constant pressure. This causes a drop in temperature and a decrease in internal energy.
Adding two negative quantities yields a negative . Once again, the gas is rejecting heat.

Analyzing Process 4

Isochoric Pressure Rise
Finally, we arrive at process 4. The path goes straight up. Just like in process 2, the volume is constant, so no work is done.
But look at the pressure—it is rising! An increase in pressure at a constant volume means the product is increasing. The temperature goes up, and so does the internal energy.
With a positive change in internal energy and zero work, is positive. The gas is absorbing heat to increase its pressure.

The Final Verdict

By systematically applying the First Law of Thermodynamics to each step, we have discovered that the gas absorbs heat only during the expansion in step 1 and the pressure rise in step 4.
Therefore, the correct answer is steps 1 and 4.

Similar Questions

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One mole of a monatomic ideal gas is taken through a cycle as shown in the diagram. Column II gives the characteristics involved in the cycle. Match them with each of the processes given in Column I.

List-I

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Comprehension Passage

In a thermodynamics process on an ideal monatomic gas, the infinitesimal heat absorbed by the gas is given by , where is temperature of the system and is the infinitesimal change in a thermodynamic quantity of the system. For a mole of monatomic ideal gas . Here, is gas constant, is volume of gas, and are constants. The List-I below gives some quantities involved in a process and List-II gives some possible values of these quantities. List-I (I) Work done by the system in process (II) Change in internal energy in process (III) Heat absorbed by the system in process (IV) Heat absorbed by the system in process List-II (P) (Q) (R) (S) (T) (U)
Question 1:

If the process carried out on one mole of monatomic ideal gas is as shown in figure in the PV-diagram with , the correct match is,

(A)
I Q, II R, III P, IV U
(B)
I S, II R, III Q, IV T
(C)
I Q, II R, III S, IV U
(D)
I Q, II S, III R, IV U
Question 2:

If the process on one mole of monatomic ideal gas is an shown is as shown in the TV-diagram with , the correct match is

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I S, II T, III Q, IV U
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