The study of thermodynamics often feels like an intricate dance between heat, work, and internal energy. In this problem, we are presented with a classic rectangular cycle on a P-V diagram. Our objective is to determine exactly where the gas is absorbing heat from its surroundings.
To unlock the secrets of this cycle, we must rely on the First Law of Thermodynamics.
The Master Equation
The First Law of Thermodynamics is essentially the law of conservation of energy applied to thermal systems. It states:
ΔQ=ΔU+W
Here, ΔQ is the heat supplied to the gas, ΔU is the change in its internal energy, and W is the work done by the gas.
For an ideal gas, the internal energy depends exclusively on its temperature. According to the ideal gas equation, PV=nRT, the temperature is directly proportional to the product of pressure and volume (PV). Therefore, if the PV product increases, the temperature rises, and ΔU is positive.
Work done, on the other hand, is geometrically represented as the area under the P-V curve. If the gas expands (volume increases), the work done is positive. If it is compressed, the work done is negative.
Analyzing Process 1
Isobaric Expansion
Let's look at the first step, labeled as process 1. The arrow points to the right, indicating that the volume is increasing while the pressure remains constant. This is an isobaric expansion.
Because the volume is increasing, the gas is doing work on its surroundings.
W1>0
Simultaneously, since the pressure is constant and the volume is increasing, their product PV is increasing. This means the temperature of the gas is rising, leading to an increase in internal energy.
ΔU1>0
Plugging these into our master equation, a positive work and a positive change in internal energy guarantee that ΔQ1 is positive. The gas is absorbing heat.
Analyzing Process 2
Isochoric Pressure Drop
Moving to process 2, the path goes straight down. The volume is perfectly constant, meaning the gas is neither expanding nor compressing. This is an isochoric process.
Since there is no change in volume, the area under the curve is zero.
W2=0
However, the pressure is dropping. A decrease in pressure at a constant volume means the PV product is decreasing. The gas is cooling down, so its internal energy decreases.
ΔU2<0
With zero work and a negative change in internal energy, ΔQ2 must be negative. The gas is rejecting heat.
Analyzing Process 3
Isobaric Compression
In process 3, the arrow points to the left. The gas is being compressed while the pressure is held constant.
Because the volume is decreasing, the work done by the gas is negative.
W3<0
The PV product is also decreasing because the volume is shrinking at a constant pressure. This causes a drop in temperature and a decrease in internal energy.
ΔU3<0
Adding two negative quantities yields a negative ΔQ3. Once again, the gas is rejecting heat.
Analyzing Process 4
Isochoric Pressure Rise
Finally, we arrive at process 4. The path goes straight up. Just like in process 2, the volume is constant, so no work is done.
W4=0
But look at the pressure—it is rising! An increase in pressure at a constant volume means the PV product is increasing. The temperature goes up, and so does the internal energy.
ΔU4>0
With a positive change in internal energy and zero work, ΔQ4 is positive. The gas is absorbing heat to increase its pressure.
The Final Verdict
By systematically applying the First Law of Thermodynamics to each step, we have discovered that the gas absorbs heat only during the expansion in step 1 and the pressure rise in step 4.
Therefore, the correct answer is steps 1 and 4.