The Setup
Accelerating through a Potential Difference
Imagine a classic physics setup: two parallel metal plates connected to a battery, creating a constant potential difference V between them. In this electric field, we place two tiny contestants at the positive plate, both starting from rest.
Our first contestant is a hydrogen ion (H+), which is essentially a bare proton. Our second contestant is a singly ionized helium atom (He+). The electric field exerts a force on both, accelerating them towards the negative plate. The question is: who crosses the finish line faster, and by what ratio?
The Master Equation
Energy Conservation
To solve this, we don't need to track their complex kinematics step-by-step. Instead, we use the elegant principle of Energy Conservation.
When a charged particle of charge q moves through a potential difference V, the electric field does work on it. This work is entirely converted into the particle's kinetic energy. Mathematically, we write this as:
Since both particles start from rest, their initial kinetic energy is zero. We can rearrange this master equation to find an expression for the final velocity v:
Notice that the potential difference V is a constant for both ions. The final velocity depends solely on the ratio of their charge to their mass, often called the specific charge.
Comparing the Contenders
Hydrogen vs. Helium
Let's analyze our two contestants based on our velocity formula.
For the Hydrogen Ion (H+):
It has a charge of +1e (where e is the elementary charge) and a mass we'll call m. Plugging these into our formula, its final velocity vH is:
For the Singly Ionized Helium Atom (He+):
"Singly ionized" means it has lost exactly one electron. Therefore, its net charge is also +1e. However, a helium nucleus contains two protons and two neutrons, making its mass approximately four times that of a hydrogen ion. So, its mass is 4m. Its final velocity vHe is:
The Final Showdown
Calculating the Ratio
Now for the grand finale. We need the ratio of their final speeds, vH:vHe. Let's divide the two expressions we just found:
Because they were accelerated through the same potential difference V, and they have the same charge e, the terms 2eV cancel out beautifully. The mass m also cancels out, leaving us with:
This means the hydrogen ion is exactly twice as fast as the singly ionized helium atom when they reach the other plate. The final ratio is 2:1.