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The Sigma Insight: Kinetic Theory of Gases
The Illusion of Macroscopic Motion
Imagine you are standing on the side of a highway, watching a massive lorry cruise past you at a perfectly uniform speed. Inside the cargo hold of this lorry sits a sealed container filled with cooking gas. A fascinating question arises: Does the fact that the lorry is moving at mean the gas inside is hotter than if the lorry were parked?
To answer this, we must dive into the microscopic world and understand what temperature truly is.
The Microscopic Definition of Temperature
In our everyday experience, we associate kinetic energy with speed. A fast-moving car has more kinetic energy than a slow one. However, temperature is not a measure of the macroscopic kinetic energy of an entire object.
Instead, temperature is a measure of the average random translational kinetic energy of the molecules, measured strictly with respect to the center of mass of the gas.
Mathematically, the random kinetic energy is given by:
Here, is the velocity of an individual molecule, and is the velocity of the center of mass of the entire gas cloud. Notice how we subtract the center of mass velocity? This is the crucial step. We only care about how the molecules are buzzing around relative to each other, not how the whole swarm is moving together.
The Effect of Uniform Motion
When the lorry moves with a uniform velocity , it imparts this exact same velocity to the container, and consequently, to every single gas molecule inside it.
Let's look at the math. The new velocity of each molecule becomes .
Similarly, the entire center of mass of the gas is now moving with the lorry, so its new velocity is .
Now, let's calculate the relative velocity that actually determines temperature:
The uniform velocity completely cancels out!
The Final Verdict
Because the relative random velocities of the molecules remain entirely unchanged, the chaotic, disordered collisions happening inside the container are exactly the same as they would be if the lorry were at rest.
Therefore, the internal random kinetic energy is constant, and the temperature of the gas remains exactly the same.
Think of it like a swarm of bees inside a moving train. The train might be moving at , but the bees are still just buzzing around each other at their normal speed. The temperature only measures the "buzzing," not the train's speed. However, if the train were to suddenly crash, that organized forward energy would violently convert into chaotic buzzing, and then the temperature would spike!
Similar Questions
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An ideal gas in a closed container is slowly heated. As its temperature increases, which of the following statements are true? A. The mean free path of the molecules decreases. B. The mean collision time between the molecules decreases. C. The mean free path remains unchanged. D. The mean collision time remains unchanged.
(A)
B and C
(B)
A and B
(C)
C and D
(D)
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The temperature of an ideal gas is increased from to . If at the root mean square velocity of the gas molecules is , at it becomes
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Three closed vessels , and at the same temperature and contain gases which obey the Maxwellian distribution of velocities. Vessel contains only , only and a mixture of equal quantities of and . If the average speed of the molecules in vessel is , that of the molecules in vessel is , the average speed of the molecules in vessel is (where, is the mass of an oxygen molecule)
(A)
(B)
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For a given gas at pressure, rms speed of the molecules is at . At pressure and at , the rms speed of the molecules will be
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A vessel contains a mixture of one mole of oxygen and two moles of nitrogen at 300 K. The ratio of the average rotational kinetic energy per molecule to per molecule is
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The rms speeds of the molecules of hydrogen, oxygen and carbondioxide at the same temperature are , and respectively, then
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From the following statements concerning ideal gas at any given temperature , select the correct one (s).
* Multiple Correct Options
(A)
The coefficient of volume expansion at constant pressure is the same for all ideal gases
(B)
The average translational kinetic energy per molecule of oxygen gas is , being Boltzmann constant
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The mean-free path of molecules increases with decrease in the pressure
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In a gaseous mixture, the average translational kinetic energy of the molecules of each component is different
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On the basis of kinetic theory of gases, the gas exerts pressure because its molecules
(A)
continuously lose their energy till it reaches wall
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are attracted by the walls of container
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continuously stick to the walls of container
(D)
suffer change in momentum when impinge on the walls of container
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Three perfect gases at absolute temperatures and are mixed. The masses of molecules are and and the number of molecules are and respectively. Assuming no loss of energy, the final temperature of the mixture is
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(B)
(C)
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In a dilute gas at pressure and temperature , the mean time between successive collisions of a molecule varies with as
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