Sigma Percentile
JEE Main 2021
LEVELJEE Main

Animated Solution for Chemistry - Atomic Structure: Given below are two statements. Statement I: According to Bohr's model of an atom, qualitatively the magnitude of velocity of electron increases with decrease in positive charges on the nucleus as there is no strong hold on the electron by the nucleus. Statement II: According to Bohr's model of an atom, qualitatively the magnitude of velocity of electron increases with decrease in principal quantum number. In the light of the above statements, choose the most appropriate answer from the options given below.

Select Answer:

Visualized Solution

  • Bohr's model describes electrons in circular orbits around a positively charged nucleus.

  • If , then

  • If , then

  • Statement I is False.
  • Statement II is True.

The Sigma Insight: Bohr's Model

Solution Diagram

The Planetary Dance of Electrons

Imagine an atom as a miniature solar system. At the very center lies a dense, positively charged nucleus, acting much like our Sun. Revolving around this nucleus are electrons, tracing out fixed, circular paths known as orbits. This elegant picture is the essence of Bohr's Model of the Atom.
But how fast are these electrons moving? Do they all travel at the same speed, or does their velocity depend on where they are and what atom they belong to? To answer this, we must look at the delicate balance of forces that keeps the electron in its orbit.

The Master Equation for Velocity

For an electron to stay in a circular orbit, the electrostatic force of attraction between the positively charged nucleus and the negatively charged electron must provide the necessary centripetal force. By combining this classical physics concept with Bohr's revolutionary postulate of quantized angular momentum (), we can derive the exact velocity of an electron in any given orbit.
The resulting formula is a cornerstone of atomic physics:
From this equation, we can extract a beautiful, simplified proportionality:
Here, represents the atomic number (the number of protons, or the positive charge on the nucleus), and is the principal quantum number (the orbit number).

Analyzing Statement I

The Pull of the Nucleus
Let's put Statement I under the microscope. It claims that the velocity of an electron increases when the positive charge on the nucleus () decreases. The reasoning provided is that a weaker hold allows the electron to move faster.
However, our master equation tells a different story. We know that . This means velocity is directly proportional to the nuclear charge. Physically, if the nucleus has a stronger positive charge (higher ), it pulls the electron inward with greater force. To avoid crashing into the nucleus, the electron must travel faster to generate a sufficient outward centripetal effect. Conversely, if decreases, the required velocity also decreases.
Therefore, Statement I is fundamentally false.

Analyzing Statement II

The Size of the Orbit
Now, let's examine Statement II. It asserts that the velocity of an electron increases as the principal quantum number () decreases.
Looking back at our proportionality, . This indicates an inverse relationship between velocity and the orbit number. When decreases, the electron is in an orbit closer to the nucleus. In these inner orbits, the electrostatic pull is incredibly strong due to the shorter distance. To maintain a stable orbit so close to the nucleus, the electron must zip around at a much higher speed.
Thus, a smaller indeed results in a higher velocity, making Statement II absolutely true.

The Final Verdict

By systematically applying the mathematical principles of Bohr's model, we have successfully decoded the physical realities behind both statements. Statement I contradicts the direct proportionality between velocity and nuclear charge, while Statement II perfectly aligns with the inverse proportionality between velocity and orbit size.
Consequently, Statement I is false, and Statement II is true, leading us to the correct conclusion.

Similar Questions

JEE Main 2021
LEVELJEE Main

According to Bohr's atomic theory, I. kinetic energy of electron is II. the product of velocity () of electron and principal quantum number (), '' . III. frequency of revolution of electron in an orbit is IV. coulombic force of attraction on the electron is Choose the most appropriate answer from the options given below.

(A)
Only III
(B)
Only I
(C)
I, III and IV
(D)
I and IV
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LEVELJEE Main

Comprehension Passage

Consider the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I contains some quantities for the orbit of the atom and List-II contains options showing how they depend on . \begin{array}{ll} \textbf{List-I} & \textbf{List-II} \\ \text{(I) Radius of the } n^{\text{th}} \text{ orbit} & \text{(P) } \propto n^{-2} \\ \text{(II) Angular momentum of the electron in the } n^{\text{th}} \text{ orbit} & \text{(Q) } \propto n^{-1} \\ \text{(III) Kinetic energy of the electron in the } n^{\text{th}} \text{ orbit} & \text{(R) } \propto n^0 \\ \text{(IV) Potential energy of the electron in the } n^{\text{th}} \text{ orbit} & \text{(S) } \propto n^1 \\ & \text{(T) } \propto n^2 \\ & \text{(U) } \propto n^{1/2} \end{array}
Question 1:

Which of the following options has the correct combination considering List-I and List-II ?

(A)
(II), (R)
(B)
(I), (P)
(C)
(I), (T)
(D)
(II), (Q)
Question 2:

Which of the following options has the correct combination considering List-I and List-II ?

(A)
(III), (S)
(B)
(IV), (Q)
(C)
(IV), (U)
(D)
(III), (P)
JEE Main 2021
LEVELJEE Main

Given below are two statements. Statement I Bohr's theory accounts for the stability and line spectrum of ion. Statement II Bohr's theory was unable to explain the splitting of spectral lines in the presence of a magnetic field. In the light of the above statements, choose the most appropriate answer from the options given below :

(A)
Both statements I and II are true.
(B)
Statement I is false but statement II is true.
(C)
Both statements I and II are false.
(D)
Statement I is true but statement II is false.
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LEVELJEE Main

For the Balmer series in the spectrum of H atom, , the correct statements among (I) to (IV) are : (I) As wavelength decreases, the lines in the series converge (II) The integer is equal to 2 (III) The lines of longest wavelength corresponds to (IV) The ionisation energy of hydrogen can be calculated from wave number of these lines

(A)
I, II, IV
(B)
II, III, IV
(C)
I, III, IV
(D)
I, II, III
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The radius of the second Bohr orbit for hydrogen atom is (Planck's constant ; mass of electron ; charge of electron ; permitivity of vacuum )

(A)
(B)
(C)
(D)
JEE Main 2021
LEVELJEE Main

The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is equal to . The value of is ……… . ( is radius of Bohr's orbit) (Nearest integer) [Given, ]

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The radius of the second Bohr orbit in terms of the Bohr radius, , in is

(A)
(B)
(C)
(D)
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Energy of an electron is given by . Wavelength of light required to excite an electron in an hydrogen atom from level to will be ( and )

(A)
(B)
(C)
(D)
JEE Advanced 2023
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For , a transition takes place from the orbit of radius to the orbit of radius . The wavelength (in nm) of the emitted photon during the transition is ______. [Use: Bohr radius, Rydberg constant, Planck's constant, Speed of light, ]

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Which of the following is the energy of a possible excited state of hydrogen?

(A)
(B)
(C)
(D)