The Planetary Dance of Electrons
Imagine an atom as a miniature solar system. At the very center lies a dense, positively charged nucleus, acting much like our Sun. Revolving around this nucleus are electrons, tracing out fixed, circular paths known as orbits. This elegant picture is the essence of Bohr's Model of the Atom.
But how fast are these electrons moving? Do they all travel at the same speed, or does their velocity depend on where they are and what atom they belong to? To answer this, we must look at the delicate balance of forces that keeps the electron in its orbit.
The Master Equation for Velocity
For an electron to stay in a circular orbit, the electrostatic force of attraction between the positively charged nucleus and the negatively charged electron must provide the necessary centripetal force. By combining this classical physics concept with Bohr's revolutionary postulate of quantized angular momentum (mvr=2πnh), we can derive the exact velocity of an electron in any given orbit.
The resulting formula is a cornerstone of atomic physics:
From this equation, we can extract a beautiful, simplified proportionality:
Here, Z represents the atomic number (the number of protons, or the positive charge on the nucleus), and n is the principal quantum number (the orbit number).
Analyzing Statement I
The Pull of the Nucleus
Let's put Statement I under the microscope. It claims that the velocity of an electron increases when the positive charge on the nucleus (Z) decreases. The reasoning provided is that a weaker hold allows the electron to move faster.
However, our master equation tells a different story. We know that v∝Z. This means velocity is directly proportional to the nuclear charge. Physically, if the nucleus has a stronger positive charge (higher Z), it pulls the electron inward with greater force. To avoid crashing into the nucleus, the electron must travel faster to generate a sufficient outward centripetal effect. Conversely, if Z decreases, the required velocity also decreases.
Therefore, Statement I is fundamentally false.
Analyzing Statement II
The Size of the Orbit
Now, let's examine Statement II. It asserts that the velocity of an electron increases as the principal quantum number (n) decreases.
Looking back at our proportionality, v∝n1. This indicates an inverse relationship between velocity and the orbit number. When n decreases, the electron is in an orbit closer to the nucleus. In these inner orbits, the electrostatic pull is incredibly strong due to the shorter distance. To maintain a stable orbit so close to the nucleus, the electron must zip around at a much higher speed.
Thus, a smaller n indeed results in a higher velocity, making Statement II absolutely true.
The Final Verdict
By systematically applying the mathematical principles of Bohr's model, we have successfully decoded the physical realities behind both statements. Statement I contradicts the direct proportionality between velocity and nuclear charge, while Statement II perfectly aligns with the inverse proportionality between velocity and orbit size.
Consequently, Statement I is false, and Statement II is true, leading us to the correct conclusion.