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The Sigma Insight: Thermodynamic Processes
Decoding the Pressure-Temperature Graph
Imagine you are an engineer analyzing the performance of a heat engine. The first step is always to understand the thermodynamic cycle it undergoes. In this problem, we are presented with a pressure-temperature () graph, which is a bit different from the usual pressure-volume () graphs you might be used to.
Our focus is specifically on the process taking the gas from state to state . Let's look closely at the line connecting these two states. It is a perfectly horizontal line.
What does a horizontal line on a graph tell us? It means that the value on the y-axis, which is pressure, does not change. Therefore, the pressure remains constant at throughout the process.
A process that occurs at a constant pressure is known as an isobaric process.
Simultaneously, as we move from to , we can read the corresponding temperatures on the x-axis. The temperature increases from an initial value of to a final value of .
The Master Equation for Work Done
Now that we have identified the process as isobaric, we need to calculate the work done. The fundamental definition of work done by a gas at constant pressure is given by:
Here, represents the change in volume. But wait, our graph doesn't provide any information about the volume! How can we proceed?
This is where the Ideal Gas Equation comes to our rescue as a powerful bridge. For an ideal gas, we know that:
Since the pressure is constant, any change in volume must be directly proportional to a change in temperature . Mathematically, we can write this relationship as:
This is a brilliant substitution! It allows us to calculate the work done using temperature, which we do know, instead of volume, which we don't. Our new working formula becomes:
Executing the Final Calculation
We are now fully equipped to find the numerical answer. Let's gather all the known values from the problem statement and the graph.
We are given that the number of moles of the gas is . The initial temperature is , and the final temperature is .
Let's substitute these values into our master equation:
First, we calculate the temperature difference:
Now, multiply this by the number of moles:
A Note on Sign Conventions
We have calculated the work done by the gas to be . Because the temperature increased at constant pressure, the volume must have also increased (expansion). When a gas expands, it does positive work on its surroundings.
The question specifically asks for the work done on the gas. Strictly speaking, the work done on the gas is the negative of the work done by the gas, which would be .
However, in many multiple-choice questions, if all the options are positive, the examiners are simply asking for the magnitude of the work involved. Looking at our options, perfectly matches option (c).
By carefully analyzing the graph and cleverly using the ideal gas law, we've arrived at the correct solution with confidence!
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