The Magic of Mixing Gases
Imagine you have two different gases in separate containers. One is a diatomic gas with γ=57 (like Oxygen or Nitrogen), and the other is a monatomic gas with γ=35 (like Helium or Argon). What happens when you mix them together? Does the new mixture behave like a monatomic gas, a diatomic gas, or something entirely different?
To find the effective γ of the mixture, we cannot simply take an average. Physics demands that we respect the fundamental laws of nature, specifically the Conservation of Internal Energy.
The Master Equation
When two non-reacting ideal gases are mixed, the total internal energy of the mixture is simply the sum of the internal energies of the individual gases:
We know that the internal energy of an ideal gas is given by U=nCvT. Substituting this into our conservation equation, we get:
(n1+n2)CvmixT=n1Cv1T+n2Cv2T
Since the temperature T is common and cancels out, and knowing that Cv=γ−1R, we arrive at our master equation for the mixture:
γmix−1n1+n2=γ1−1n1+γ2−1n2
Executing the Calculation
Now, let's bring in the values from our problem. We have 1 mol of each gas, so n1=1 and n2=1. Their respective gamma values are γ1=57 and γ2=35. Substituting these into our master equation:
γmix−11+1=57−11+35−11
Let's simplify the denominators carefully. For the first gas, 57−1=52. For the second gas, 35−1=32. Plugging these back in:
Inverting the fractions on the right side gives:
Adding the fractions yields 28, which simplifies to 4. So, we have:
Rearranging to solve for γmix−1:
Finally, adding 1 to both sides gives us our answer:
The Examiner's Trap
You might look at the options and panic because 23 is nowhere to be found! But don't rush. Look closely at option (c), which is 1624. If you divide the numerator and the denominator by 8, you get exactly 23. The examiner set a clever little trap to test your confidence in your own calculation. Always trust your math!